Skip to main content
Log in

Li2Se-As2Se3 pseudobinary join in the Li-As-Se system and properties of LiAsSe2

  • Published:
Inorganic Materials Aims and scope

Abstract

Phase relations in the pseudobinary system Li2Se-As2Se3 have been studied using physicochemical characterization techniques. The Li2Se-As2Se3 system contains one chemical compound, LiAsSe2, which melts congruently at 808 K and undergoes a polymorphic transformation at 737 K. Some physicochemical and electrical properties of the LiAsSe2 compound have been studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Golovei, M.I., Semrad, E.E., and Luzhnaya, N.P., Preparation and Properties of Alkali-Metal Metaselenoarsenites, Zh. Neorg. Khim, 1969, vol. 14, no. 11, pp. 2932–2936.

    CAS  Google Scholar 

  2. Voroshilov, Yu.V., Golovei, M.I., Semrad, E.E., and Peresh, E.Yu., Crystal Structures of Alkali-Metal Metachalcogenoarsenites and Metachalcogenobismuthites, Vsesoyuznaya konferentsiya po kristallokhimii intermetallicheskikh soedinenii. Tezisy dokladov (All-Union Conf. on Crystal Chemistry of Intermetallic Compounds: Abstracts), Lvov, 1971, p. 20.

  3. Dovgoshei, N.I., Nikolyuk, V.I., Semrad, E.E., et al., Electrical Properties of Alkali-Metal Metaselenoarsenites, Izv. Vyssh. Uchebn. Zaved. Fiz., 1970, vol. 13, no. 3, pp. 393–394.

    Google Scholar 

  4. Semrad, E.E., Preparation and Properties of Alkali-Metal Metaselenoarsenites, Extended Abstract of Cand. (Chem.) Sci. Dissertation, Kiev, 1972.

  5. Eisenmann, B. and Schäfer, H., Über Seleno- und Telluroarsenite, -antimonite und -bismutite, Z. Anorg. Allg. Chem., 1979, vol. 456, pp. 87–94.

    Article  CAS  Google Scholar 

  6. Sheldrick, W.S. and Häusler, H.-J., Zur Kenntnis von Alkalimetaselenoarseniten Darstellung und Kristallstrukturen von MAsSe2, M = K, Rb, Cs, Z. Anorg. Allg. Chem., 1988, vol. 561, pp. 139–148.

    Article  CAS  Google Scholar 

  7. Bera, T.K., Joon I. Jang, Jung-Hwan Song, et al., Soluble Semiconductors AAsSe2 (A = Li, Na) with a Direct-Band-Gap and Strong Second Harmonic Generation: A Combined Experimental and Theoretical Study, J. Am. Chem. Soc., 2010, vol. 132, pp. 3484–3495.

    Article  CAS  Google Scholar 

  8. Johnston, W.D. and Heikes, R.R., A Study of the System LixMn(1 − x)Se, J. Am. Chem. Soc., 1958, vol. 80, pp. 5904–5907.

    Article  CAS  Google Scholar 

  9. Smith, R.L. and Sandland, G.E., An Accurate Method of Determining the Hardness of Metals, with Particular Reference to Those of a High Degree of Hardness, Proc. Inst. Mech. Eng., 1922, vol. 1, pp. 623–641.

    CAS  Google Scholar 

  10. Hillebrand, W.F., Lundell, G.E.F., Bright, H.A., and Hoffman, J.I., Applied Inorganic Analysis with Special Reference to the Analysis of Metals, Minerals, and Rocks, New York: Wiley, 1953, 2nd ed.

    Google Scholar 

  11. Kreshkov, A.P., Osnovy analiticheskoi khimii (Fundamentals of Analytical Chemistry), Moscow: Khimiya, 1971, vol. 2.

    Google Scholar 

  12. Nazarenko, I.I. and Ermakov, A.N., Analiticheskaya khimiya selena i tellura (Analytical Chemistry of Selenium and Tellurium), Moscow: Nauka, 1971.

    Google Scholar 

  13. Kivilis, S.S., Tekhnika izmereniya plotnosti zhidkosti i tverdykh tel (Density Measurements for Liquids and Solids), Moscow: Standartizdat, 1959.

    Google Scholar 

  14. Day, M.C., Jr. and Selbin, J., Theoretical Inorganic Chemistry, New York: Reinhold, 1969, 2nd ed.

    Google Scholar 

  15. Sangster, J. and Pelton, A.D., The Li-Se (Lithium-Selenium) System, J. Phase Equilib., 1997, vol. 18, pp. 181–184.

    Article  CAS  Google Scholar 

  16. Okamoto, H., As-Se (Arsenic-Selenium), J. Phase Equilib., 1998, vol. 19, p. 488.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. I. Sidei.

Additional information

Original Russian Text © E.E. Semrad, V.I. Sidei, A.M. Solomon, 2013, published in Neorganicheskie Materialy, 2013, Vol. 49, No. 3, pp. 236–239.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Semrad, E.E., Sidei, V.I. & Solomon, A.M. Li2Se-As2Se3 pseudobinary join in the Li-As-Se system and properties of LiAsSe2 . Inorg Mater 49, 235–238 (2013). https://doi.org/10.1134/S0020168513030187

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168513030187

Keywords

Navigation