Skip to main content
Log in

Physicochemical interaction at the MnSi1.71–1.75/Mo interface

  • Published:
Inorganic Materials Aims and scope

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

Diffusion processes at the interface between higher manganese silicide (HMS) MnSi1.71–1.75 and Mo at elevated temperatures have been studied by microstructural analysis and X-ray microanalysis. The results demonstrate the formation of a reaction diffusion zone at the HMS/metal interface. The compositions of the phases identified in intermediate layers are consistent with phase equilibria in the ternary system Mn-Mo-Si, and their electrical and thermal conductivity is high enough not to create an energy barrier in the contact zone with the semiconductor. The thermal expansion mismatch between the phases in contact may degrade the bonding between the layers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Dudkin, L.D. and Petrova, L.I., Prospects of Using Unconventional Thermoelectric Materials in Small-Scale Energetics, Perspekt. Mater., 1996, no. 5, pp. 15–26.

    Google Scholar 

  2. Zaitsev, V.K., Thermoelectric Properties of Anisotropic MnSi1.75, Handbook of Thermoelectrics, Rowe, D.M., Ed., New York: CRC, 1995, pp. 299–309.

    Google Scholar 

  3. Zaitsev, V.K., Fedorov, M.I., and Andreev, A.A., Kinetic Properties of Thermoelectrics Based on the Higher Manganese Silicide, Termoelektriki i ikh primeneniya. XII Mezhgosudarstvennyi seminar (Thermoelectric Materials and Their Applications: XII Int. Seminar), St. Petersburg: Fiziko-Tekh. Inst. im. A.F. Ioffe, 2010, pp. 94–98.

    Google Scholar 

  4. Suvorova, E.I., Solomkin, F.Yu., Kantoni, M., and Bufa, F.A., Electron Microscopy of Impurities and Impurity Precipitates in Doped Transition Metal Silicides, Termoelektriki i ikh primeneniya. XII Mezhgosudarstvennyi seminar (Thermoelectric Materials and Their Applications: XII Int. Seminar), St. Petersburg: Fiziko-Tekh. Inst. im. A.F. Ioffe, 2010, pp. 253–256.

    Google Scholar 

  5. Diagrammy sostoyaniya dvoinykh metallicheskikh sistem. Spravochnik (Phase Diagrams of Binary Metallic Systems: A Handbook), Lyakishev, N.P., Ed., Moscow: Mashinostroenie, vol. 3, part 1, 1999.

    Google Scholar 

  6. Gmelin Handbook of Inorganic Chemistry, vol. C8: Manganese, Berlin: Springer, 1982.

  7. Rydnik, V.I. and Borovskii, I.B., Quantitative X-ray Microanalysis, Zavod. Lab., 1967, no. 8, pp. 955–961.

    Google Scholar 

  8. Gel’d, P.V. and Sidorenko, F.A., Silitsidy perekhodnykh metallov chetvertogo perioda (3d-TransitionMetal Silicides), Moscow: Metallurgiya, 1971.

    Google Scholar 

  9. Hultgren, R., Desai, P.D., Hawkins, D.T., et al., Selected Values of the Thermodynamic Properties of the Binary Alloys, Metals Park: ASM International, 1973, pp. 1158–1163.

    Google Scholar 

  10. Frenkel, J. and Sergeev, M.I., Interdiffusion of Metals through Intermetallic Compounds, Zh. Eksp. Teor. Fiz., 1939, vol. 9, no. 2, pp. 189–198.

    CAS  Google Scholar 

  11. Arzamasov, M.I., Determination of the Reaction Diffusion Coefficient, Metalloved. Term. Obrab. Mater., 1967, no. 3, pp. 49–51.

    Google Scholar 

  12. Thomas, O., Senateur, J.P., Madar, R., et al., Molybdenum Disilicide: Crystal Growth, Thermal Expansion and Resistivity, Solid State Commun., 1985, vol. 55, pp. 629–632.

    Article  CAS  Google Scholar 

  13. Samsonov, G.V., Tugoplavkie soedineniya. Spravochnik po svoistvam i primeneniyu (Properties and Applications of Refractory Compounds: A Handbook), Moscow: Metallurgizdat, 1963.

    Google Scholar 

  14. Tablitsy fizicheskikh velichin. Spravochnik (Tables of Physical Quantities: A Handbook), Kikoin, I.K, Ed., Moscow: Atomizdat, 1976.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to L. I. Petrova.

Additional information

Original Russian Text © L.I. Petrova, M.I. Fedorov, V.K. Zaitsev, A.E. Engalychev, 2013, published in Neorganicheskie Materialy, 2013, Vol. 49, No. 4, pp. 367–371.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Petrova, L.I., Fedorov, M.I., Zaitsev, V.K. et al. Physicochemical interaction at the MnSi1.71–1.75/Mo interface. Inorg Mater 49, 355–358 (2013). https://doi.org/10.1134/S0020168513030151

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168513030151

Keywords

Navigation