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Crystal structure of a new neodymium hexamolybdotellurate, Nd2TeMo6O24 · 19H2O

  • Structure of Inorganic Compounds
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Abstract

The crystal structure of a new compound, namely, Nd2TeMo6O24 · 19H2O, is determined using X-ray diffraction. The crystal has a chain structure and consists of [Nd2TeMo6O24 · 14H2O]n neutral chains aligned parallel to the [010] direction and crystallization water molecules. In a chain, each Nd atom links two heteropoly anions. The Nd3+ environment includes seven water molecules and two oxygen atoms of the two heteropoly anions adjacent in the chain. The polyhedron is a monocapped tetragonal antiprism. In the previously studied complex of similar composition, namely, Nd2TeMo6O24 · 18H2O, the Nd coordination polyhedron has the shape of a tricapped trigonal prism formed by six water molecules and three oxygen atoms of the two heteropoly anions adjacent in the chain.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    I. A. Charushnikova, A. M. Fedoseev & A. B. Yusov

  2. CEA Marcoule, DRCP/SCPS/LCAM, Bagnols-sur-Céze, 30207, France

    C. Den Auwer

Authors
  1. I. A. Charushnikova
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  2. A. M. Fedoseev
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  3. A. B. Yusov
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  4. C. Den Auwer
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Translated from Kristallografiya, Vol. 50, No. 2, 2005, pp. 223–225.

Original Russian Text Copyright © 2005 by Charushnikova, Fedoseev, Yusov, Den Auwer.

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Charushnikova, I.A., Fedoseev, A.M., Yusov, A.B. et al. Crystal structure of a new neodymium hexamolybdotellurate, Nd2TeMo6O24 · 19H2O. Crystallogr. Rep. 50, 191–193 (2005). https://doi.org/10.1134/1.1887892

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  • DOI: https://doi.org/10.1134/1.1887892

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