Russian Journal of Organic Chemistry

, 47:766

Synthesis and molecular structures of dibenzo(perhydrotriazino)aza-14-crown-4 ethers

  • Chyong Khong Khieu
  • A. T. Soldatenkov
  • An’ Le Tuan
  • A. N. Levov
  • A. F. Smol’yakov
  • V. N. Khrustalev
  • M. Yu. Antipin
Article

DOI: 10.1134/S1070428011050174

Cite this article as:
Khieu, C.K., Soldatenkov, A.T., Le Tuan, A. et al. Russ J Org Chem (2011) 47: 766. doi:10.1134/S1070428011050174

Abstract

By triple condensation of thiourea or guanidine with 1,ω-bis(2-formylphenoxy)-3-oxapentane and ammonium acetate first representatives of the new class of ethers bis(benzo)aza-14-crown-4 were obtained in 28–73% yield that included as a subunit a symm-perhydrotriazine ring. This reaction also proceeds readily with N-monomethyl- and N-monopropenyl-substituted thioureas affording the corresponding derivatives of triazinoazacrown ether. At the same time urea in the similar condensation does not form the expected perhydrotriazinoazacrown ether. The molecular structure of one perhydroazacrown ether as a complex with a chloroform molecule was established by XRD analysis.

Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  • Chyong Khong Khieu
    • 1
  • A. T. Soldatenkov
    • 1
  • An’ Le Tuan
    • 2
  • A. N. Levov
    • 1
  • A. F. Smol’yakov
    • 3
  • V. N. Khrustalev
    • 3
  • M. Yu. Antipin
    • 3
  1. 1.Russian University of Peoples’ FriendshipMoscowRussia
  2. 2.Hanoi University of SciencesVietnam State UniversityHanoiVietnam
  3. 3.Nesmeyanov Institute of Organoelemental CompoundsRussian Academy of SciencesMoscowRussia