, Volume 82, Issue 6, pp 935-939
Date: 25 Jul 2009

Synthesis and study of solid solutions between cobalt and nickel phosphates with varied degree of anion protonation

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Abstract

Continuous substitutional solid solutions between cobalt and nickel phosphates with varied degree of anion protonation were obtained: Co1−x Ni x HPO4·1.5H2O and (Co1−x Ni x )3(PO4)2·8H2O, where 0 ≤ x ≤ 1.00. The thermolysis of the solid solutions was studied by the example of Co1−x Ni x HPO4·1.5H2O. The phases synthesized were compared with the previously described continuous solid solution Co1−x Ni x (H2PO4)2·2H2O.

Original Russian Text © V.N. Viter, P.G. Nagornyi, 2009, published in Zhurnal Prikladnoi Khimii, 2009, Vol. 82, No. 6, pp. 881–885.