Synthesis and structure of triphenylantinony dimethacrylate

  • A. V. Gushchin
  • D. V. Shashkin
  • L. K. Prytkova
  • N. V. Somov
  • E. V. Baranov
  • A. S. Shavyrin
  • V. I. Rykalin
Article

DOI: 10.1134/S107036321103008X

Cite this article as:
Gushchin, A.V., Shashkin, D.V., Prytkova, L.K. et al. Russ J Gen Chem (2011) 81: 493. doi:10.1134/S107036321103008X
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Abstract

Triphenylantinony dimethacrylate Ph3Sb(O2CMe=CH2)2 was obtained in the reaction of triphenylantimony with methacrylic acid in the presence of hydrogen peroxide. The structure of the product was confirmed by elemental analysis, IR and 1H NMR spectroscopy. According to X-ray diffraction analysis the substance is a trigonal bipyramidal complex of antimony with three phenyl groups in its basis and two methacrylate groups at the bipyramid vertices.

Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  • A. V. Gushchin
    • 1
  • D. V. Shashkin
    • 1
  • L. K. Prytkova
    • 1
  • N. V. Somov
    • 1
  • E. V. Baranov
    • 2
  • A. S. Shavyrin
    • 2
  • V. I. Rykalin
    • 3
  1. 1.Lobachevskii Nizhnii Novgorod State UniversityNizhnii NovgorodRussia
  2. 2.Razuvaev Institute of Organometallic ChemistryRussian Academy of SciencesNizhnii NovgorodRussia
  3. 3.State Research CenterInstitute of High Energy PhysicsProtvino, Moscow OblastRussia