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Direct electrochemical and chemical syntheses, structures, and properties of metal complexes of azo compounds with an additional azo group in the amine fragment

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Abstract

New complexes of Cu(II), Co(II), and Ni(II) with 1-phenyl-3-methyl-4-[(4-phenylazophenyl)hydrazono]-5H-pyrazol-5-one and 1-phenyl-3-methyl-4-[4-methyl-2-(4-methylphenylazophenyl)hydrazono]-5H-pyrazol-5-one are synthesized by the chemical and electrochemical methods and characterized by IR, 1H NMR, and EXAFS spectroscopy and X-ray diffraction analysis. Depending on the complexing metal and position of the additional azo group, the latter is involved or not in coordination with the metal to form heterounit five- and six-membered metallocycles.

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References

  1. Troyanov, I.A., Lipinskaya, L.G., Divaeva, L.N., et. al., USSR Inventor’s Certificate 682521, Byull. Izobret., 1982, no. 45.

    Google Scholar 

  2. Divaeva, L.N., Simonov, A.M., Kolodyazhnaya, S.N., et. al., USSR Inventor’s Certificate 979349, Byull. Izobret., 1982, no 45.

    Google Scholar 

  3. Chernov’yants, M.S., Evlashenkova, I.V., and Divaeva, L.N., Zh. Org. Khim., 1996, vol. 32, no. 12.

    Google Scholar 

  4. Chernov’yants, M.S., Evlashenkova, I.V., Kuplevatskaya, N.V., et al., Zh. Anal. Khim., 1996, vol. 52, no. 9, p. 931.

    Google Scholar 

  5. Chernov’yants, M.S., Evlashenkova, I.V., and Divaeva, L.N., Zh. Anal. Khim., 1996, vol. 51, no. 9, p. 935.

    Google Scholar 

  6. Chigarenko, G.G., Ponomarenko, A.G., Burlov, A.S., et al., Trenie i Iznos, 2007, vol. 28, no. 4, p. 397.

    CAS  Google Scholar 

  7. Barchan, G.P., Chigarenko, G.G., Kogan, V.A., et al., USSR Inventor’s Certificate 810778, Byull. Izobret., 1981, no. 9.

    Google Scholar 

  8. Barchan, G.P., Chigarenko, G.G., Bolotnikov, V.S., et al., USSR Inventor’s Certificate 910741, Byull. Izobret., 1982, no. 9.

    Google Scholar 

  9. Emeleus, L.C., Cupertino, D.C., Harris, S.G., et al., Dalton Trans., 2001, p. 1239.

    Google Scholar 

  10. Garnovskii, A.D., Alekseenko, V.A., Burlov, A.S., and Nedzvetskii, V.S., Zh. Neorg. Khim., 1991, vol. 36, no. 4, p. 886.

    CAS  Google Scholar 

  11. Garnovskii, A.D., Burlov, A.S., Antsyshkina, A.S., and Divaeva, L.N., Russ. J. Inorg. Chem., 1996, vol. 41, no. 1, p. 90.

    CAS  Google Scholar 

  12. Kogan, V.A. and Shcherbakov, I.N., Ross. Khim. Zh., 2004, vol. 48. no. 1, p. 69.

    Google Scholar 

  13. Garnovskii, A.D. and Vasil’chenko, I.S., Usp. Khim., 2005, vol. 74, no. 3, p. 211.

    Article  Google Scholar 

  14. Burlov, A.S., Uraev, A.I., Ikorskii, V.A., et al., Russ. J. Gen. Chem., 2008, vol. 78, no. 6, p. 1230.

    Article  CAS  Google Scholar 

  15. Burlov, A.S., Nikolaevskii, S.A., Bogomyakov, A.S., et al., Russ. J. Coord. Chem., 2009, vol. 35, no. 7, p. 486.

    Article  CAS  Google Scholar 

  16. Garnovskii, A.D., Burlov, A.S., Starikov, A.G., et al., Russ. J. Coord. Chem., 2010, vol. 36, no. 7, p. 479.

    Article  CAS  Google Scholar 

  17. Gütlich, P., Garcia, Y., and Wolke, T., Coord. Chem. Rev., 2001, vol. 219–222, p. 839.

    Article  Google Scholar 

  18. Wang, P., Ming, H., Zhang, J.Y., et al., Opt. Commun., 2002, vol. 203, p. 159.

    Article  CAS  Google Scholar 

  19. Nivorozhkin, A.L., Toftlund, H., Nivorozhkin, L.E., et al., Transition Met. Chem., 1994, vol. 19, no. 4, p. 319.

    CAS  Google Scholar 

  20. Chernyshov, A.A., Veligzhanin, A.A., and Zubavichus, Y.V., Nucl. Instr. Meth. Phys. Res. A, 2009, vol. 603, p. 95.

    Article  CAS  Google Scholar 

  21. Kochubei, D.I., Babanov, Yu.A., Zamaraev, K.I., et al., Rentgenospektral’nyi metod izucheniya struktury amorfnykh tel: EXAFS-spektroskopiya (X-ray Spectral Method of Investigation of Structures of Amorphous Solids: EXAFS Spectroscopy), Novosibirsk: Nauka. Sib. otd., 1988, p. 306.

    Google Scholar 

  22. Newville, M., J. Synchrotron Rad., 2001, vol. 8, p. 96.

    Article  CAS  Google Scholar 

  23. Zabinski, S.I., Rehr, J.J., Ankudinov, A., and Alber, R.C., Phys. Rev., vol. 52, p. 2995.

  24. SMART (control) and SAINT (integration) Software, Version 5.0, Madison (WI, USA): Bruker AXS Inc., 1997.

  25. Sheldrik, G.M., SADABS, Program for Scanning and Correction of Area Detector Data, Götinngen (Germany): Univ. of Götinngen, 1997.

    Google Scholar 

  26. SHELXS-97 and SHELXL-97, Götinngen (Germany): Univ. of Göttingen, 1997.

  27. Weber, B., Coord. Chem. Rev., 2009, vol. 253, p. 2432.

    Article  CAS  Google Scholar 

  28. Alekseenko, V.A., Kogan, V.A., Burlov, A.S., et al., Zh. Neorg. Khim., 1985, vol. 30, no. 1, p. 252.

    CAS  Google Scholar 

  29. Alekseenko, V.A., Burlov, A.S., Divaeva, L.N., et al., Zh. Neorg. Khim., 1988, vol. 33, no. 9, p. 2307.

    CAS  Google Scholar 

  30. Burlov, A.S., Antsyshkina, A.S., Sadikov, G.G., et al., Russ. J. Coord. Chem., 2000, vol. 26, no. 9, p. 648.

    CAS  Google Scholar 

  31. Antsyshkina, A.S., Sadikov, G.G., Burlov, A.S., et al., Kristallografiya, 2000, vol. 45, no. 6, p. 1019.

    CAS  Google Scholar 

  32. Burlov, A.S., Antsyshkina, A.S., Sadikov, G.G., et al., J. Coord. Chem., 2010, vol. 63, no. 6, p. 917.

    Article  CAS  Google Scholar 

  33. Burlov, A.S., Antsyshkina, A.S., Sadikov, G.G., et al., Mendeleev Commun., 2011, vol. 27, p. 87.

    Article  Google Scholar 

  34. Kochin, S.G., Antsyshkina, A.S., Sadikov, G.G., et al., Dokl. Ross. Akad. Nauk, 1997, vol. 355, no. 6, p. 777.

    CAS  Google Scholar 

  35. Burlov, A.S., Uraev, A.I., Matuev, P.V., et al., Rus. J. Coord. Chem., 2008, vol. 34, no. 12, p. 904.

    Article  CAS  Google Scholar 

  36. Kogan, V.A., Kochin, S.G., Antsyshkina, A.S., et al., Mendeleev Commun., 1999, no. 2, p. 82.

    Google Scholar 

  37. Kogan, V.A., Lyubchenko, S.N., Shcherbakov, I.N., et al., Rus. J. Coord. Chem., 2005, vol. 31, no. 8, p. 533.

    Article  CAS  Google Scholar 

  38. Dyachenko, O.A., Atovmyan, L.O., and Aldoshin, S.M., Chem. Commun., 1975, no. 4, p. 105.

    Google Scholar 

  39. Morkovnik, A.S., Divaeva, L.N., Uraev, A.I., et. al., Izv. Ross. Akad. Nauk, Ser. Khim., 2008, no. 7, p. 1467.

    Google Scholar 

  40. Kuz’mina, L.G., Grigor’eva, L.P., and Struchkov, Yu.T., Khim. Geterotsikl. Soedin., 1985, no. 6, p. 816.

    Google Scholar 

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Authors and Affiliations

  1. Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia

    A. S. Burlov, S. A. Mashchenko, S. A. Nikolaevskii, A. I. Uraev & E. V. Korshunova

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. S. Antsyshkina, G. G. Sadikov, V. S. Sergienko & M. A. Kiskin

  3. Research Institute of Physics, Southern Federal University, Rostov-on-Don, Russia

    V. G. Vlasenko

  4. Kurchatov Institute Russian Research Center, pl. Kurchatova 1, Moscow, 123182, Russia

    Ya. V. Zubavichus

  5. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    D. A. Garnovskii & S. I. Levchenkov

Authors
  1. A. S. Burlov
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  2. S. A. Mashchenko
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  3. A. S. Antsyshkina
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  4. G. G. Sadikov
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  5. V. S. Sergienko
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  6. M. A. Kiskin
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  7. S. A. Nikolaevskii
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  8. V. G. Vlasenko
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  9. Ya. V. Zubavichus
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  10. A. I. Uraev
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  11. D. A. Garnovskii
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  12. E. V. Korshunova
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  13. S. I. Levchenkov
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Corresponding author

Correspondence to A. S. Burlov.

Additional information

Original Russian Text © A.S. Burlov, S.A. Mashchenko, A.S. Antsyshkina, G.G. Sadikov, V.S. Sergienko, M.A. Kiskin, S.A. Nikolaevskii, V.G. Vlasenko, Ya.V. Zubavichus, A.I. Uraev, D.A. Garnovskii, E.V. Korshunova, S.I. Levchenkov, 2013, published in Koordinatsionnaya Khimiya, 2013, Vol. 39, No. 12, pp. 707–715.

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Burlov, A.S., Mashchenko, S.A., Antsyshkina, A.S. et al. Direct electrochemical and chemical syntheses, structures, and properties of metal complexes of azo compounds with an additional azo group in the amine fragment. Russ J Coord Chem 39, 813–821 (2013). https://doi.org/10.1134/S1070328413120014

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  • DOI: https://doi.org/10.1134/S1070328413120014

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