Synthesis and characterization of a novel complex [Pd(Bipy)2](Bpcc) · 11H2O
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- Gao, E.J., Zhang, Y.X., Zhu, M.C. et al. Russ J Coord Chem (2010) 36: 853. doi:10.1134/S1070328410110114
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The complex [Pd(Bipy)2](Bpcc) · 11H2O has been synthesized and characterized (Bipy = 2,2′-bipyridyl, H2Bpcc = 4,4′-biphenylcarboxylic acid). The supramolecular architecture was constructed through hydrogen bonding and π-π-stacking. The Pd atom is four-coordinated and forms a distorted square geometry. The free H2O molecules form 1D infinite zigzag chains of water cluster, while the water cluster and Bpcc2− form an organic-water framework.