, Volume 117, Issue 6, pp 1139-1163
Date: 29 Jan 2014

Dispersion transition and the nonergodicity of the disordered nanoporous medium-nonwetting liquid system

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Abstract

The experiments in which a nonwetting liquid does not flow from a disordered nanoporous medium are described. The outflow is shown to depend on the degree of filling of the porous medium and its temperature in a critical manner. A physical mechanism is proposed where the transition of a system of liquid nanoclusters in a confinement into a metastable state in narrow filling and temperature ranges results from the appearance of a potential barrier due to the fluctuations of the collective “multiparticle” interaction of liquid nanoclusters in neighboring pores of different sizes at the shell of a percolation cluster of filled pores. The energy of a metastable state forms a potential relief with numerous maxima and minima in the space of a porous medium. The dispersed liquid volume in a metastable state is calculated with an analytical percolation theory for a ground state with an infinite percolation cluster. The outflow time distribution function of pores is calculated, and a power law is obtained for the decrease in nonwetting liquid volume retained in a porous medium with increasing time. The relaxation of the system under study is a multistage process accompanied by discontinuous equilibrium and overcoming of numerous local maxima of a potential relief. The formation of the metastable state of retained nonwetting liquid results from the nonergodicity properties of a disordered porous medium. The proposed model can describe the detected dependences of dispersed liquid volume on the degree of filling and temperature.

Original Russian Text © V.D. Borman, A.A. Belogorlov, V.A. Byrkin, V.N. Tronin, V.I. Troyan, 2013, published in Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2013, Vol. 144, No. 6, pp. 1290–1318.