, Volume 52, Issue 1, pp 28-36

Crystal chemistry and prediction of compounds with a structure of skutterudite type

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Abstract

Crystallochemical analysis of skutterudite-type structures in the BX 3, AB 4 X 12, and AB3 B 4O12 compositions (A and B are metals; X = P, As, Sb) has been performed. Probable regions of structure formation are determined, thereby indicating that more than 270 new compounds of the AB 4 X 12 composition can be synthesized.

Original Russian Text © K.S. Aleksandrov, B.V. Beznosikov, 2007, published in Kristallografiya, 2007, Vol. 52, No. 1, pp. 32–40.
Dedicated to the 50th Anniversary of the Journal