, Volume 55, Issue 4, pp 484-493
Date: 05 May 2010

Synthesis of Ba4R3F17 (R stands for rare-earth elements) powders and transparent compacts on their base

Rent the article at a discount

Rent now

* Final gross prices may vary according to local VAT.

Get Access

Abstract

Single-phase samples of Ba4R3F17 · nH2O (R = La, Ce, Pr, Nd, Eu, Gd, Y, Er, or Yb; n = 2.5−3.2) were prepared by coprecipitation from nitrate solutions using hydrofluoric acid. The phases crystallize in a fluorite-type face-centered cubic lattice. The dried precipitates are transparent. Scanning electron and atomic-force microscopy and X-ray diffraction line broadening show a hierarchic structure in the samples: primary nanoparticles join into agglomerates with characteristic sizes of about 150–200 nm, these agglomerates being self-packed into parallel layers with a thickness on the order of 500 nm.

Original Russian Text © S.V. Kuznetsov, P.P. Fedorov, V.V. Voronov, K.S. Samarina, R.P. Ermakov, V.V. Osiko, 2010, published in Zhurnal Neorganicheskoi Khimii, 2010, Vol. 55, No. 4, pp. 536–545.