Kinetics and Catalysis

, Volume 52, Issue 1, pp 98–103

Electrical conductivity of magnesium oxide as a catalyst for radical chain hydrocarbon pyrolysis reactions

Article

DOI: 10.1134/S0023158411010204

Cite this article as:
Vasil’eva, N.A. & Uvarov, N.F. Kinet Catal (2011) 52: 98. doi:10.1134/S0023158411010204

Abstract

The electrical conductivity of polycrystalline MgO between 350 and 750°C is determined by the transport of surface electronic and hole defects and depends on the applied voltage. Near 620°C at low applied voltages, the conductivity decreases by 1–2 orders of magnitude in a narrow temperature range (ΔT = 75°C), and this is accompanied by a change of the sign of the surface charge carriers. The “ignition” of the catalytic activity of magnesium oxide in free radical generation in radical chain hydrocarbon pyrolysis is observed in the same temperature range. It is assumed that the change of the sign of the charge carriers is due to the existence of an isoelectric temperature Ti and that, at T > Ti, OO· defects come out to the magnesium oxide surface.

Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  1. 1.Boreskov Institute of Catalysis, Siberian BranchRussian Academy of SciencesNovosibirskRussia
  2. 2.Institute of Solid State Chemistry and Mechanochemistry, Siberian BranchRussian Academy of SciencesNovosibirskRussia