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Nanoporous solvate of N,N-phthaloyl-glycine

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Abstract

N,N-phthaloyl-glycine is synthesized under microwave activation without solvent. Its nanoporous solvate is obtained by recrystallization. The solvate is studied by single crystal and powder XRD, thermogravimetry, and mass spectrometry. The crystals are composed of dimers that form a framework structure with infinite channels of about 4 Å in diameter, containing a non-stoichiometric amount of chloroform (the mole fraction is close to 0.35). The nature of the incorporated solvate molecules is determined by high-resolution mass spectrometry, and their quantity is found by thermogravimetry.

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Authors and Affiliations

  1. Novosibirsk State University, Novosibirsk, Russia

    N. A. Tumanov, N. A. Pankrushina & E. V. Boldyreva

  2. Institute of Solid State Chemistry and Mechanochemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    N. A. Tumanov & E. V. Boldyreva

  3. N. N. Vorozhtsov Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    N. A. Pankrushina & A. A. Nefedov

Authors
  1. N. A. Tumanov
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  2. N. A. Pankrushina
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  3. A. A. Nefedov
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  4. E. V. Boldyreva
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Correspondence to N. A. Tumanov.

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Original Russian Text Copyright © 2012 by N. A. Tumanov, N. A. Pankrushina, A. A. Nefedov, E. V. Boldyreva

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Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 3, pp. 611–614, May–June, 2012.

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Tumanov, N.A., Pankrushina, N.A., Nefedov, A.A. et al. Nanoporous solvate of N,N-phthaloyl-glycine. J Struct Chem 53, 606–609 (2012). https://doi.org/10.1134/S0022476612030298

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  • DOI: https://doi.org/10.1134/S0022476612030298

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