Inorganic Materials

, Volume 46, Issue 9, pp 988–993

Composition, structural parameters, and color of langatate

  • I. A. Kaurova
  • G. M. Kuz’micheva
  • V. B. Rybakov
  • A. B. Dubovskii
  • A. Cousson
Article

DOI: 10.1134/S0020168510090128

Cite this article as:
Kaurova, I.A., Kuz’micheva, G.M., Rybakov, V.B. et al. Inorg Mater (2010) 46: 988. doi:10.1134/S0020168510090128

Abstract

Langatate crystals with the nominal composition La3(Ga0.5Ta0.5)Ga5O14 grown by Czochralski pulling along 〈0001〉 have been studied by X-ray and neutron diffraction before and after postgrowth annealing in air and vacuum. Their compositions are determined, the relationship between the Ga/Ta ratio and unit-cell parameters is established, and their color (colorless, yellow, and orange crystals) is shown to depend on their oxygen content and the growth and annealing conditions. Vacuum annealing at sufficiently high temperatures leads to precipitation of a green phase, La(Ta,Ga)3+O3.

Copyright information

© Pleiades Publishing, Ltd. 2010

Authors and Affiliations

  • I. A. Kaurova
    • 1
  • G. M. Kuz’micheva
    • 1
  • V. B. Rybakov
    • 2
  • A. B. Dubovskii
    • 3
  • A. Cousson
    • 4
  1. 1.Lomonosov State Academy of Fine Chemical TechnologyMoscowRussia
  2. 2.Moscow State UniversityMoscowRussia
  3. 3.Moscow State Open University (Aleksandrov Branch)Aleksandrov, Vladimir oblastRussia
  4. 4.Laboratoire Léon BrillouinCEA SaclayGif-sur-YvetteFrance