Crystallography Reports

, Volume 49, Issue 4, pp 614–618

Synthesis and investigation of the new phosphates K2LnZr(PO4)3 (Ln = Ce-Yb, Y) with langbeinite Structure

  • I. G. Trubach
  • A. I. Beskrovnyi
  • A. I. Orlova
  • V. A. Orlova
  • V. S. Kurazhkovskaya
Structure of Inorganic Compounds

DOI: 10.1134/1.1780625

Cite this article as:
Trubach, I.G., Beskrovnyi, A.I., Orlova, A.I. et al. Crystallogr. Rep. (2004) 49: 614. doi:10.1134/1.1780625

Abstract

New orthophosphates of potassium, zirconium, and rare earth elements K2LnZr(PO4)3 (Ln = Ce-Yb, Y) that crystallize in a langbeinite structure (cubic system, sp. gr. P213, Z = 4) were prepared and investigated by X-ray diffraction and IR spectroscopy. The structure of the K2PrZr(PO4)3 phosphate was refined by the Rietveld method using neutron powder diffraction data (DN-2 time-of-flight diffractometer, Joint Institute for Nuclear Research, Dubna). This structure is characterized by a mixed framework [PrZr(PO4)3] with large cavities in which potassium cations are located. Pr3+ and Zr4+ cations are distributed in order over two independent crystallographic positions. The limits of the incorporation of lanthanide cations into the anionic framework in phosphates with sodium-zirconium phosphate and langbeinite structures are considered.

Copyright information

© MAIK "Nauka/Interperiodica" 2004

Authors and Affiliations

  • I. G. Trubach
    • 1
  • A. I. Beskrovnyi
    • 2
  • A. I. Orlova
    • 1
  • V. A. Orlova
    • 1
  • V. S. Kurazhkovskaya
    • 3
  1. 1.Nizhni Novgorod State UniversityNizhni NovgorodRussia
  2. 2.Joint Institute for Nuclear ResearchDubna, Moscow oblastRussia
  3. 3.Moscow State UniversityVorob’evy gory, MoscowRussia