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Synthesis and structure of triphenylantinony dimethacrylate

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Abstract

Triphenylantinony dimethacrylate Ph3Sb(O2CMe=CH2)2 was obtained in the reaction of triphenylantimony with methacrylic acid in the presence of hydrogen peroxide. The structure of the product was confirmed by elemental analysis, IR and 1H NMR spectroscopy. According to X-ray diffraction analysis the substance is a trigonal bipyramidal complex of antimony with three phenyl groups in its basis and two methacrylate groups at the bipyramid vertices.

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Authors and Affiliations

  1. Lobachevskii Nizhnii Novgorod State University, pr. Gagarina 23, Nizhnii Novgorod, 603950, Russia

    A. V. Gushchin, D. V. Shashkin, L. K. Prytkova & N. V. Somov

  2. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russia

    E. V. Baranov & A. S. Shavyrin

  3. State Research Center, Institute of High Energy Physics, Protvino, Moscow Oblast, Russia

    V. I. Rykalin

Authors
  1. A. V. Gushchin
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  2. D. V. Shashkin
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  3. L. K. Prytkova
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  4. N. V. Somov
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  5. E. V. Baranov
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  6. A. S. Shavyrin
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  7. V. I. Rykalin
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Corresponding author

Correspondence to A. V. Gushchin.

Additional information

Original Russian Text © A.V. Gushchin, D.V. Shashkin, L.K. Prytkova, N.V. Somov, E.V. Baranov, A.S. Shavyrin, V.I. Rykalin, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 3, pp. 397–400.

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Gushchin, A.V., Shashkin, D.V., Prytkova, L.K. et al. Synthesis and structure of triphenylantinony dimethacrylate. Russ J Gen Chem 81, 493–496 (2011). https://doi.org/10.1134/S107036321103008X

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  • DOI: https://doi.org/10.1134/S107036321103008X

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