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Nature of Contamination and Preparation of Pure Precipitates of Rh(III) and Ir(III) Ammonium Sodium Hexanitrites

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Abstract

Various spectroscopic methods and X-ray phase analysis were applied to study the distribution of copper(II) and lead(II) between the solution and the precipitate of (NH4)2Na[Rh(NO2)6]. Promising methods are proposed for fine purification of ammonium sodium hexanitrites of rhodium(III) and iridium(III) to remove contaminants, irrespective of the mechanism of their ingress into crystalline phases.

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REFERENCES

  1. Lebedinskii, V.V. and Shenderetskaya, E.V., Izv. Sekt. Platiny, 1955, no. 29, pp. 61-65.

  2. Muraveiskaya, G.S., Chernyaev, I.I., and Sorokina, V.F., Zh. Neorg. Khim., 1963, vol. 8, no. 3, pp. 578-582.

    Google Scholar 

  3. Leidie, E., C. R. Acad. Sci. Paris, 1890, vol. 111, pp. 106-115.

    Google Scholar 

  4. Wichers, E., Gilchrist, R., and Swendger, Wm.H., Purification of the Six Platinum Metals, Technical Publication of the American Inst. of Mining and Metals Engineering, March, 1928, no. 87.

  5. Mamonov, S.N., Sorkinova, G.A., and Ryumin, A.I., Abstracts of Papers, XV Chernyaevskoe soveshchanie po khimii, analizu i tekhnologii platinovykh metallov (XV Chernyaev Meet. on Chemistry, Analysis, and Technology of Platinum Metals), Moscow, 1993, p. 311.

  6. Venediktov, A.B., Gomboeva, Ts.N., and Belyaev, A.V., Koord. Khim., 1985, vol. 11, no. 3, pp. 346-351.

    Google Scholar 

  7. Schwarzenbach, G. und Flaschka, H., Die Komplexometrische Titration, Stuttgart: Ferdinand Enke, 1965.

    Google Scholar 

  8. Venediktov, A.B. and Korenev, S.V., Sib. Khim. Zh., 1991, no. 6, pp. 48-52.

  9. Gromilov, S.A., Baidina, I.A., Alekseev, V.I., et al., Zh. Neorg. Khim., 1990, vol. 35, no. 3, pp. 682-684.

    Google Scholar 

  10. Gromilov, S.A., Khranenko, S.P., Belyaev, A.V., et al., Abstracts of Papers, VI Vsesoyuznyi simpozium po izomorfizmu (VI All-Union Symp. on Isomorphism), Zvenigorod, 1988, p. 61.

  11. Abragam, A. and Bleaney, B., Electron Paramagnetic Resonance of Transition Ions, Oxford: Clarendon, 1970.

    Google Scholar 

  12. Cavalca, L., Nardelli, M., and Grazioli, D., Gazz. Chim. Ital., 1956, vol. 86, no. 11, pp. 1041-1047.

    Google Scholar 

  13. Sillen, L.G. and Martell, A.E., Stability Constants of Metal-Ion Complexes. London: Chem. Soc., Burlington House, 1967.

    Google Scholar 

  14. Korenev, S.V., Gromilov, S.A., and Venediktov, A.B., Zh. Strukt. Khim., 1994, vol. 35, no. 1, pp. 141-145.

    Google Scholar 

  15. Lur'e, Yu.Yu., Spravochnik po analiticheskoi khimii (Handbook of Analytical Chemistry), Moscow: Khimiya, 1967.

    Google Scholar 

  16. Venediktov, A.B., Tkachev, S.V., and Korenev, S.V., Koord. Khim., 1997, vol. 23, no. 9, pp. 690-700.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    S. V. Korenev, A. B. Venediktov, V. A. Nadolinnyi & A. V. Belyaev

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  1. S. V. Korenev
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  2. A. B. Venediktov
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  3. V. A. Nadolinnyi
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  4. A. V. Belyaev
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Korenev, S.V., Venediktov, A.B., Nadolinnyi, V.A. et al. Nature of Contamination and Preparation of Pure Precipitates of Rh(III) and Ir(III) Ammonium Sodium Hexanitrites. Russian Journal of Applied Chemistry 74, 7–11 (2001). https://doi.org/10.1023/A:1012758908776

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