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Synthesis of Nanocrystalline High-Temperature Zirconia Phases

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Abstract

The formation of ZrO2 nanocrystals during heat treatment of amorphous ZrO(OH)2 is studied. The results indicate that the high-temperature phases of ZrO2 (T-ZrO2 and trace amounts of C-ZrO2) can be produced and stabilized at 350–375°C in nanoparticles with a size of coherently scattering domains on the order of 20 nm. Heating to above 500–600°C leads to the formation and growth of the stable phase M-ZrO2. The nature of the starting zirconium salt is shown to have a significant effect on the thermal decomposition of zirconium hydroxides.

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Authors and Affiliations

  1. Moscow Engineering Physics Institute (State University), Kashirskoe sh. 31, Moscow, 115409, Russia

    V. F. Petrunin, V. V. Popov,  Zhu Hongzhi & A. A. Timofeev

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  1. V. F. Petrunin
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  2. V. V. Popov
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  3. Zhu Hongzhi
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  4. A. A. Timofeev
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Petrunin, V.F., Popov, V.V., Zhu Hongzhi et al. Synthesis of Nanocrystalline High-Temperature Zirconia Phases. Inorganic Materials 40, 251–258 (2004). https://doi.org/10.1023/B:INMA.0000020523.89340.46

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  • DOI: https://doi.org/10.1023/B:INMA.0000020523.89340.46

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