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Kinetic studies on the acid catalyzed reaction of hydroxamic acids in β-cyclodextrin/surfactant mixed systems

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Abstract

The acid catalyzed hydrolysis of two N-substituted hydroxamic acids (C6H5CON(OH)R′, R′ = C6H5 (PBHA), R′ = C6H5CH2(BBHA)) in mixed systems containing β-cyclodextrin (β—CD) and a surfactant (sodium dodecyl sulfate, SDS) has been studied. The reactions are inhibited by β—CD. The inhibition is attributed to the formation of inclusion complex and competition between the micellization and complexation processes.

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Authors and Affiliations

  1. School of Studies in Chemistry, Pt. Ravishankar Shukla University, Raipur, 492010, India

    Kallol K. Ghosh, Pokhraj Sharma & Samiksha Taramkar

  2. Department of Engineering Chemistry, Bhilai Institute of Technology, Durg, 491001

    Santosh Kumar Sar

Authors
  1. Kallol K. Ghosh
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  2. Pokhraj Sharma
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  3. Samiksha Taramkar
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  4. Santosh Kumar Sar
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Correspondence to Kallol K. Ghosh.

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Ghosh, K.K., Sharma, P., Taramkar, S. et al. Kinetic studies on the acid catalyzed reaction of hydroxamic acids in β-cyclodextrin/surfactant mixed systems. Reaction Kinetics and Catalysis Letters 81, 161–168 (2004). https://doi.org/10.1023/B:REAC.0000016530.60292.b8

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  • DOI: https://doi.org/10.1023/B:REAC.0000016530.60292.b8

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