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Reactions of tert-Butyl Tetraethylphosphorodiamidite with Acetic and Trifluoroacetic Acids

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Abstract

Reactions of tert-butyl tetraethylphosphorodiamidite with acetic and trifluoroacetic acids involve substitution of the amido group. This process was described by a scheme beginning with protonation of phosphorus and proved by modeling separate reaction stages. A probable scheme of the proposed reactions is described.

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Authors and Affiliations

  1. Buketov Karaganda State University, Karaganda, Kazakhstan

    L. K. Sal'keeva, M. T. Nurmagambetova, O. Sh. Kurmanaliev & T. Kh. Gazizov

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  1. L. K. Sal'keeva
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  2. M. T. Nurmagambetova
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  3. O. Sh. Kurmanaliev
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  4. T. Kh. Gazizov
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Sal'keeva, L.K., Nurmagambetova, M.T., Kurmanaliev, O.S. et al. Reactions of tert-Butyl Tetraethylphosphorodiamidite with Acetic and Trifluoroacetic Acids. Russian Journal of General Chemistry 73, 183–186 (2003). https://doi.org/10.1023/A:1024723517711

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  • DOI: https://doi.org/10.1023/A:1024723517711

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