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Thermodynamic properties of liquid Al-Si and Al-Cu alloys

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Abstract

The partial and integral enthalpies of mixing in liquid Al-Si and Al-Cu alloys were determined by high-temperature isoperibolic calorimetry at 1750±5 and 1590±5, respectively. The thermodynamic properties of Al-Si melts were also studied by electromotive force method in temperature range 950-1270 K. The partial and integral excess Gibbs free energies of mixing in liquid Al-Si and Al-Cu alloys were also calculated from literature data on thermodynamic activity of aluminium. The comparison of our experimental results with literature data has been performed.

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Authors and Affiliations

  1. Taras Shevchenko University, 64, Volodymyrska Str., 01033, Kiev, Ukraine

    D. S. Kanibolotsky, O. A. Bieloborodova, N. V. Kotova & V. V. Lisnyak

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  1. D. S. Kanibolotsky
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  2. O. A. Bieloborodova
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  3. N. V. Kotova
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  4. V. V. Lisnyak
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Correspondence to V. V. Lisnyak.

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Kanibolotsky, D.S., Bieloborodova, O.A., Kotova, N.V. et al. Thermodynamic properties of liquid Al-Si and Al-Cu alloys. Journal of Thermal Analysis and Calorimetry 70, 975–983 (2002). https://doi.org/10.1023/A:1022285010138

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