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Selective hydrogenation of ά,β-unsaturated aldehydes and other C=O and C=C bonds containing compounds

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Abstract

Advances in developing new heterogeneous catalysts which hydrogenate preferentially the C=O group of ά,β-unsaturated aldehydes to obtain the desired products, namely unsaturated alcohols, will be reviewed by considering the parameters which control the intramolecular selectivity: support material, nature and particle size of the individual metals, selective poisoning, presence of a second metal, preparation method or catalyst precursor, temperature of reduction, host-guest interactions in zeolites, substituents on the C=C bond and pressure effects. Recent attempts with bimetallic and silver catalysts to hydrogenate only the C=O group of other polyfunctional organic compounds in the gas phase without simultaneous hydrogenation of aromatic or furan rings will be shown.

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  1. Department Catalysis, Institute for Applied Chemistry, Rudower Chaussee 5, D-12489, Berlin, Germany

    Peter Claus

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Claus, P. Selective hydrogenation of ά,β-unsaturated aldehydes and other C=O and C=C bonds containing compounds. Topics in Catalysis 5, 51–62 (1998). https://doi.org/10.1023/A:1019177330810

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