Skip to main content
Log in

Crystal structure and spectroscopic characterization of bis(N-phenylthiourea)

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Bis(N-phenylthiourea) (BPTU) has been synthesized and characterized by means of X-ray, IR, Raman, UV-Vis, 1H NMR, and FAB mass spectra. The BPTU crystal belongs to the monoclinic C2/c space group with the cell constants a = 26.992(8) Å, b = 6.336(3) Å, c = 9.463(3) Å, α = γ = 90°, β = 105.97(7)°, Z = 4. The compound has been found to exist in the thione form, with cis configuration of the thiosemicarbazone moiety and skew conformation of the molecule.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Davarski, K.; Schuster, G.; Vasilev, G. J. Phytopathol. 1989, 125, 133.

    Google Scholar 

  2. Lambert, A.S. Brit. Pat. APPl. GB 2267852 1993. Chem. Abstr. 120, 169451.

    Google Scholar 

  3. Seada, M.; Abdel Rahman, R.M.; Abdel Megid, M. Indian J. Heterocycl. Chem. 1993, 3,9.

    Google Scholar 

  4. Broda, W.; Dehmlow, E.V. Isr. J. Chem. 1985, 26, 219.

    Google Scholar 

  5. Campbell, M.J.M. Coord. Chem. Rev. 1975, 15, 279.

    Google Scholar 

  6. Furlani, C.; Tarantelli, T. Gazz. Chim. Ital. 1973, 103, 951.

    Google Scholar 

  7. Akinchan, N.T.; Akinchan, R.; Ibok, U.J.; Battaglia, L.P.; Corradi, A.B.; Drożdżewski; P. J. Cryst. Spectr. Res. 1992, 22, 741.

    Google Scholar 

  8. Sheldrick, G.M. SHELX76, Program for Crystal Structure Determination; University of Cambridge: England, 1976.

    Google Scholar 

  9. Nardelli, M. Comput. Chem. 1983, 7, 95.

    Google Scholar 

  10. Farrugia, J.L. J. Appl. Cryst. 1997, 30, 565.

    Google Scholar 

  11. Kalman, A.; Argay, G.; Czugler, M. Cryst. Struct. Commun. 1972, 1, 375.

    Google Scholar 

  12. Shova, S.G.; Simonov, Y.D.; Arion, V.B.; Revenko, M.D.; Melinovskii, T.I. Dokl. Akad. Nauk SSR, 1985, 282, 1142.

    Google Scholar 

  13. Andreetti, G.D.; Domiano, P.; Fava, G.G.; Nardelli, M.; Sgarabotto, P. Acta Cryst. 1970, B26, 1005.

    Google Scholar 

  14. Akinchan, N.T.; West, D.X.; Yang, Y.H.; Salberg, M.M.; Klein, T.L. Transiton Met. Chem. 1995, 20, 481.

    Google Scholar 

  15. Heinisch, G.; Holzer, W. Monatsh. Chem. 1990, 121, 837.

    Google Scholar 

  16. Akinchan, N.T.; Drożdżewski, P.; Akinchan, R. Polish J. Chem. 2000, 74, 1221.

    Google Scholar 

  17. Gosavi, R.K.; Agarwala, U.; Rao, C.N.R. J. Am. Chem. Soc. 1967, 89, 235.

    Google Scholar 

  18. Bulka, E.; Ehlers, D. J. Prakt. Chem. 1973, 315, 155.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Piotr M. Drożdżewski.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Akinchan, N.T., Drożdżewski, P.M. & Battaglia, L.P. Crystal structure and spectroscopic characterization of bis(N-phenylthiourea). Journal of Chemical Crystallography 32, 91–97 (2002). https://doi.org/10.1023/A:1015616911355

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1015616911355

Navigation