Journal of Porous Materials

, Volume 9, Issue 1, pp 49–56

In Situ Formation of a Novel Nanocomposite Structure Based on MCM-41 and Polyethylene

Authors

  • J. He
    • The Key Laboratory of Science and Technology of Controllable Chemical ReactionsBeijing University of Chemical Technology, Ministry of Education
  • X. Duan
    • The Key Laboratory of Science and Technology of Controllable Chemical ReactionsBeijing University of Chemical Technology, Ministry of Education
  • D.G. Evans
    • The Key Laboratory of Science and Technology of Controllable Chemical ReactionsBeijing University of Chemical Technology, Ministry of Education
  • R.F. Howe
    • School of ChemistryThe University of New South Wales
Article

DOI: 10.1023/A:1014360023070

Cite this article as:
He, J., Duan, X., Evans, D. et al. Journal of Porous Materials (2002) 9: 49. doi:10.1023/A:1014360023070

Abstract

M41S materials are prepared by in situ assembly of inorganic precursors and organic template and can be viewed as nanocomposites of the siliceous phase and organic surfactant. Calcination of these precursors gives the M41S materials that have been used to prepare novel nanocomposite structures, in which the organic phase inside the nano-sized pores is isolated by the nano-sized inorganic pore walls. The nanocomposite structures can be formed by in situ polymerization of monomers inside the channels. Polymerization of ethylene takes place inside the nano-sized pores, producing the desired nanocomposite structure. The resulting polyethylene was found to be a mixture of crystalline and amorphous phases.

nanocompositein situ formationM41Spolyethylene

Copyright information

© Kluwer Academic Publishers 2002