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Transformations of cycloalkanes under the action of organoaluminum compounds and transition metal complexes in the presence of polychloromethanes

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Abstract

A catalytic system comprising an organoaluminum compound, polychloromethane, and a transition metal complex transforms cyclohexane into dimethyldecalins, cyclooctane into dimethyl- and ethylcyclohexanes, and endo-tricyclo[5.2.1.02,6]decane into its exo-isomer under mild conditions.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Academy of Sciences of the Republic Bashkortostan and Ufa Research Center of the Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    R. A. Sadykov, M. G. Samokhina & U. M. Dzhemilev

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  1. R. A. Sadykov
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  2. M. G. Samokhina
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  3. U. M. Dzhemilev
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Sadykov, R.A., Samokhina, M.G. & Dzhemilev, U.M. Transformations of cycloalkanes under the action of organoaluminum compounds and transition metal complexes in the presence of polychloromethanes. Russian Chemical Bulletin 50, 1326–1329 (2001). https://doi.org/10.1023/A:1014047915995

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  • DOI: https://doi.org/10.1023/A:1014047915995

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