Skip to main content
SpringerLink
Log in

Clathrate and Inclusion Compounds. Part 12. Vibrational and NMR Spectroscopic Studies of Carboxylic Acid Guests in Dianin's Compound

  • Published:
Journal of inclusion phenomena and molecular recognition in chemistry Aims and scope Submit manuscript

Abstract

Infrared, Raman and solid state 13C-NMR spectra have been recorded for a range of clathrates of Dianin's compound containing straight chain aliphatic carboxylic acids (formic - octanoic) as guests. The IR, Raman and NMR spectra can be satisfactorily interpreted in terms of dimer (formic and acetic) and monomer (propionic - octanoic) occupation of the cavities. The clathrates containing straight chain alcohol guests (methanol - octanol) have also been prepared to aid in the interpretation of the NMR data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Part 11. J.E.D. Davies and V.A. Tabner: J. Incl. Phenom. 11, 389 (1991).

    Google Scholar 

  2. D. D. MacNicol: in Inclusion Compounds, J.L. Atwood, J.E.D. Davies and D. D. MacNicol (Eds.), Academic Press, London, Vol. 2, pp. 1'45 (1984).

    Google Scholar 

  3. W. Baker, A.J. Floyd, J.F.W. McOmie, G. Pope, A.S. Weaving and J.H. Wild: J. Chem. Soc.2010 (1956).

  4. M. Davies and W.C. Child: Spectrochim. Acta 21, 1195 (1965).

    Google Scholar 

  5. J.E.D. Davies, R.W.H. Small and V.A. Tabner: in preparation.

  6. J.E.D. Davies: Comp. Enhanced Spectrosc. 3, 73 (1986).

    Google Scholar 

  7. K.J. Harrington: J. Therm. Anal. 28, 121 (1983).

    Google Scholar 

  8. J.E.D. Davies: J. Incl. Phenom. 3, 269 (1985).

    Google Scholar 

  9. J.A. Ripmeester and C.I. Ratcliffe: in Spectroscopic and Computational Studies of Supramolecular Systems,J.E.D. Davies (Ed.), Kluwer Academic, Dordrecht, pp. 1–27 (1992).

    Google Scholar 

  10. J.E.D. Davies and V.A. Knott: J. Mol. Struct. 174, 229 (1988).

    Google Scholar 

  11. F. Lee, E. Gabe, J.S. Tse and J.A. Ripmeester: J. Am. Chem. Soc. 110, 6014 (1988); F. Imashiro: J. Am. Chem. Soc. 115, 2231 (1993).

    Google Scholar 

  12. J.A. Ripmeester: J. Incl. Phenom. 1, 87 (1983/84).

    Google Scholar 

  13. J.L. Flippen, J. Karle and I.L. Karle: J. Am. Chem. Soc. 92, 3749 (1970).

    Google Scholar 

  14. J.L. Flippen and J. Karle: J. Phys. Chem. 75, 3566 (1971).

    Google Scholar 

  15. J.D. Roberts, F.J. Weigert, J.I. Kroschwitz and H.J. Reich: J. Am. Chem. Soc. 92, 1338 (1970).

    Google Scholar 

  16. P.C. Goswami, P. de Mayo, N. Ramnath, G. Bernard, N. Omkaram, J.R. Scheffer and Y.-F. Wong: Can. J. Chem. 63, 2719 (1985).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Environmental Science Division, Lancaster University, Lancaster, Lancs., LA1 4YQ, U.K

    J. Eric D. Davies & Vivienne A. Tabner

Authors
  1. J. Eric D. Davies
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Vivienne A. Tabner
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Davies, J.E.D., Tabner, V.A. Clathrate and Inclusion Compounds. Part 12. Vibrational and NMR Spectroscopic Studies of Carboxylic Acid Guests in Dianin's Compound. Journal of Inclusion Phenomena 27, 179–190 (1997). https://doi.org/10.1023/A:1007958323076

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1007958323076

Search

Navigation