Abstract
The synthesis, characterization and comparison of the enantiomeric transition metal complexes, trans-[Rh-(S-(−)-nicH+)4Cl2](PF6)5 and trans-[Rh-(R-(+)-nicH+)4Cl2](PF6)5, and of the racemic mixture trans-[Rh-(RS-(±)-nicH+)4Cl2](PF6)5 are described.
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R.D. Gillard, R.J. Bromfield, R.H. Dainty and B.T. Heaton, Nature, 233, 735 (1969).
R.D. Gillard, J.D. Pedrosa de Jesus and A.Y.A. Mohammad, Transition Met. Chem., 14, 258 (1989).
A. Pictet and A. Rotschy, Chem. Ber., 28, 1224 (1904).
Y. Tsujino, S. Shibata, A. Katsuyama, T. Kisaki and H. Kaneko, Heterocycles, 19, 2151 (1982).
W.B. Edwards and R. McCuen, J. Org. Chem., 48, 2484 (1983).
M. Katsuyama, J. Ferm. Tech., 61 (1983).
M.C. DeTraglia and A.M. Tometsko, Appl. Env. Microb., 39, 1067 (1980).
R.R. Bowman, H. McKennis and B.R. Martin, Synth. Commun., 12, 871 (1982).
M. Aceto and B.R. Martin, J. Med. Chem., 22, 174 (1979).
R.D. Gillard and J.D. Pedrosa de Jesus, Croat. Chem. Acta, 62, 151 (1989).
R.D. Gillard and G. Wilkinson, Inorg. Synth., 10, 64 (1967).
B.E. Mann and C.M. Spencer, Inorg. Chim. Acta, 65, L57 (1982).
B.E. Mann and C.M. Spencer, Inorg. Chim. Acta, 76, L65 (1983).
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Gillard, R.D., Lekkas, E. Complex compounds with rhodium(III) of enantiomers of nicotine. Transition Metal Chemistry 25, 617–621 (2000). https://doi.org/10.1023/A:1007088115719
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DOI: https://doi.org/10.1023/A:1007088115719