Abstract
Complexes derived from 4-substituted-2-nitrosophenols, 3-Me-2-nitrosophenol, nitrosophyrogallol, nitrososalicylic acid and nitrosogallic acid with cobalt(II), nickel(II) and copper(II) have been prepared and characterized by elemental analysis, electronic and vibrational spectra, together with magnetic susceptibility measurements. The e.s.r. spectra of the copper(II) complexes were investigated, and detailed thermal properties of selected complexes are discussed.
Similar content being viewed by others
References
M. S. Masoud, A. M. Khalil and I. Abd. El-Wawad, Indian J. Chem., 15, 468 (1977).
M. S. Masoud, M. M. Osman and H. El-Naggar, Z. Anal. Chem., 289, 207 (1978).
M. S. Masoud and S. A. Ghonaim, Pol. J. Chem., 54, 651 (1980).
M. S. Masoud, T. M. Salem and M. El-Essawi, Synth. React. Inorg. Met-Org. Chem., 13, 79 (1983).
M. S. Masoud, B. S. Farag, Y. Sawan, T. M. Salem and M. El-Essawi, J. Non-Cryst. Solids, 55, 209 (1983).
M. S. Masoud, A. El-Dessouky and S. S. Haggag, Spectrosc Lett., 18, 251 (1985).
M. S. Masoud, A. El-Dessouky and E. E. Ghatwary, Transition Met. Chem., 11, 161 (1986), Polyhedron, 5, 1867 (1986), Inorg. Chim. Acta, 141, 119 (1988).
M. S. Masoud, M. El-Essawi and A. M. Amr, Rev. Inorg. Chem., 19, 253 (1988).
M. S. Masoud, Z. Zaki and F. M. Ismail, Thermochim. Acta, 156, 225 (1989).
M. S. Masoud, S. S. Haggag and S. Abou El-Enein, Delta J. Sci., 14, 1511 (1990).
M. S. Masoud, M. A. El-Dessouky, F.A. Aly and S. Abou El-Enein, Transition Met. Chem., 15, 443 (1990).
M. S. Masoud, A. M. Hindawy, A. El-Dessouky, G.B. Mohamed and T.M. Abd El-Fattah, Transition Met. Chem., 16, 181 (1991).
M. S. Masoud, A. El-Dessouky, H. M. El-Nahas and E. E. Ghatwary, Pol. J. Chem., 65, 49 (1991).
M. S. Masoud and S. S. Haggag, Thermochim. Acta, 196, 221 (1992).
M. S. Masoud, O. H. Abd El-Hamid and Z. M. Zaki, Transition Met. Chem., 19, 21 (1994).
C. L. Walters, Chem. Br., 13, 140 (1977).
A. I. Vogel, A Text Book of Practical Organic Chemistry, Longman, London, 1962.
G. Schwarzenbach, Complexometric Titration, Metheun Co., London, 1959.
A. I. Vogel, A Text Book of Quantitative Inorganic Analysis, Longman, London, 1964.
R. H. Lee, E. Griswold and J. Kleinberg, Inorg. Chem., 3, 1278 (1964).
S. Satapathy and B. Sahoo, J. Inorg. Nucl. Chem., 32, 2223 (1970).
K. Nakamoto and R. E. Rundle, J. Am. Chem. Soc., 78, 1113 (1956).
R. A. Krause, N. B. Coltup and D. H. Busch, J. Phys. Chem., 65, 2216 (1961).
B. G. Cowenlock and W. Lüttke, Quart. Rev., 12, 321 (1958).
R. L. Williams, R. J. Pace and G. J. Jeacocke, Spectrochim. Acta, 20, 225 (1964).
A. T. Pilipenko, L. L. Shevchenko, T. A. Pavlova and V. V. Trachevskü, lzv. Vyssh. Uchelon. Zaved., Khim. Khim. Tekhnol., 23, 939 (1980).
J. R. Massaguer, J. S. Casas, J. Sordo, M. R. Bermejo and M. V. Castano, Inorg. Chim. Acta, 24, 227 (1977).
C. J. Popp and R. O. Ragsdale, Inorg. Chem., 7, 1845 (1968).
J. Charalambous, G. Soobramanien, A. Betts and J. Bailey, Inorg. Chim. Acta, 60, 151 (1982).
F. A. Cotton, Advanced Inorganic Chemistry, 3rd Edit., Wiley Eastern, London, 1979.
K. Jorgensen, Absorption Spectra and Chemical Bonding in Complexes, Pergamon Press, Oxford, 1962.
P. W. Ball and A. B. Blake, J. Chem. Soc. (A), 1415 (1969).
B. T. Thaker and P. K. Battacharya, Indian J. Chem., 14, 619 (1976).
R. S. Drago, Physical Methods in Inorganic Chemistry, Affiliated East-West Press PVI, Ltd., New Delhi, 1979.
E. M. Boge, D. P. Freyberg, E. Kokot, G. M. Mockler and E. Sinn, Inorg. Chem., 16, 1655 (1977).
J. Charalambous, M. J. Frazer and F. B. Taylar, J. Chem. Soc. (A), 2787 (1969).
B. J. Hathaway, R. J. Dudley and P. Nicholls, J. Chem. Soc. (A), 1845 (1969).
B. J. Hathaway, I. M. Procter, R. C. Slade and A. A. G. Tomlinson, J. Chem. Soc. (A), 2219 (1969).
B. J. Hathaway in J. N. Bradley and R. D. Gillard (Eds), Essays in Chemistry, Academic Press, 1971, p. 61.
F. K. Kneubuhl, J. Chem. Phys., 33, 1074 (1960).
D. W. Smith, J. Chem. Soc. (A), 3108 (1970).
S. Chandra, K. B. Pandeya and R. P. Singh, J. Indian Chem. Soc., 58, 1097 (1981).
B. J. Hathaway and D. E. Billing, Coord. Chem. Rev., 5, 143 (1970).
G. Krishramoorthy and B. S. Prabhanda, J. Phys. Chem., 84, 639 (1980).
J. Reedijk, Transition Met. Chem., 6, 195 (1981).
H. Langfelderová and O. Hodúr, J. Therm. Anal., 42, 973 (1994).
A. N. Nesmeyanov and N. A. Nesmeyanov, Fundamentals of Organic Chemistry, Mir Publishers, Moscow, 1977, Vol. 3, p. 226.
H. R. Oswald and E. Dubler in H. G. Wiedemann (Ed.), Thermal Analysis, Birkhäuser Verlag, Basel und Stuttgart, Switzerland, 1972, Vol. 2, p. 667.
H. Horowitz and G. Metzger, Anal. Chem., 35, 1464 (1963).
M. L. Dhar and O. Singh, J. Therm. Anal., 37, 259 (1991).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Masoud, M.S., Haggag, S.S., Ramadan, A.M. et al. Nitrosophenol complexes of transition metal salts. Transition Metal Chemistry 23, 343–348 (1998). https://doi.org/10.1023/A:1006909409145
Issue Date:
DOI: https://doi.org/10.1023/A:1006909409145