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Nitrosophenol complexes of transition metal salts

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Abstract

Complexes derived from 4-substituted-2-nitrosophenols, 3-Me-2-nitrosophenol, nitrosophyrogallol, nitrososalicylic acid and nitrosogallic acid with cobalt(II), nickel(II) and copper(II) have been prepared and characterized by elemental analysis, electronic and vibrational spectra, together with magnetic susceptibility measurements. The e.s.r. spectra of the copper(II) complexes were investigated, and detailed thermal properties of selected complexes are discussed.

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References

  1. M. S. Masoud, A. M. Khalil and I. Abd. El-Wawad, Indian J. Chem., 15, 468 (1977).

    Google Scholar 

  2. M. S. Masoud, M. M. Osman and H. El-Naggar, Z. Anal. Chem., 289, 207 (1978).

    Google Scholar 

  3. M. S. Masoud and S. A. Ghonaim, Pol. J. Chem., 54, 651 (1980).

    Google Scholar 

  4. M. S. Masoud, T. M. Salem and M. El-Essawi, Synth. React. Inorg. Met-Org. Chem., 13, 79 (1983).

    Google Scholar 

  5. M. S. Masoud, B. S. Farag, Y. Sawan, T. M. Salem and M. El-Essawi, J. Non-Cryst. Solids, 55, 209 (1983).

    Google Scholar 

  6. M. S. Masoud, A. El-Dessouky and S. S. Haggag, Spectrosc Lett., 18, 251 (1985).

    Google Scholar 

  7. M. S. Masoud, A. El-Dessouky and E. E. Ghatwary, Transition Met. Chem., 11, 161 (1986), Polyhedron, 5, 1867 (1986), Inorg. Chim. Acta, 141, 119 (1988).

    Google Scholar 

  8. M. S. Masoud, M. El-Essawi and A. M. Amr, Rev. Inorg. Chem., 19, 253 (1988).

    Google Scholar 

  9. M. S. Masoud, Z. Zaki and F. M. Ismail, Thermochim. Acta, 156, 225 (1989).

    Google Scholar 

  10. M. S. Masoud, S. S. Haggag and S. Abou El-Enein, Delta J. Sci., 14, 1511 (1990).

    Google Scholar 

  11. M. S. Masoud, M. A. El-Dessouky, F.A. Aly and S. Abou El-Enein, Transition Met. Chem., 15, 443 (1990).

    Google Scholar 

  12. M. S. Masoud, A. M. Hindawy, A. El-Dessouky, G.B. Mohamed and T.M. Abd El-Fattah, Transition Met. Chem., 16, 181 (1991).

    Google Scholar 

  13. M. S. Masoud, A. El-Dessouky, H. M. El-Nahas and E. E. Ghatwary, Pol. J. Chem., 65, 49 (1991).

    Google Scholar 

  14. M. S. Masoud and S. S. Haggag, Thermochim. Acta, 196, 221 (1992).

    Google Scholar 

  15. M. S. Masoud, O. H. Abd El-Hamid and Z. M. Zaki, Transition Met. Chem., 19, 21 (1994).

    Google Scholar 

  16. C. L. Walters, Chem. Br., 13, 140 (1977).

    Google Scholar 

  17. A. I. Vogel, A Text Book of Practical Organic Chemistry, Longman, London, 1962.

    Google Scholar 

  18. G. Schwarzenbach, Complexometric Titration, Metheun Co., London, 1959.

    Google Scholar 

  19. A. I. Vogel, A Text Book of Quantitative Inorganic Analysis, Longman, London, 1964.

    Google Scholar 

  20. R. H. Lee, E. Griswold and J. Kleinberg, Inorg. Chem., 3, 1278 (1964).

    Google Scholar 

  21. S. Satapathy and B. Sahoo, J. Inorg. Nucl. Chem., 32, 2223 (1970).

    Google Scholar 

  22. K. Nakamoto and R. E. Rundle, J. Am. Chem. Soc., 78, 1113 (1956).

    Google Scholar 

  23. R. A. Krause, N. B. Coltup and D. H. Busch, J. Phys. Chem., 65, 2216 (1961).

    Google Scholar 

  24. B. G. Cowenlock and W. Lüttke, Quart. Rev., 12, 321 (1958).

    Google Scholar 

  25. R. L. Williams, R. J. Pace and G. J. Jeacocke, Spectrochim. Acta, 20, 225 (1964).

    Google Scholar 

  26. A. T. Pilipenko, L. L. Shevchenko, T. A. Pavlova and V. V. Trachevskü, lzv. Vyssh. Uchelon. Zaved., Khim. Khim. Tekhnol., 23, 939 (1980).

    Google Scholar 

  27. J. R. Massaguer, J. S. Casas, J. Sordo, M. R. Bermejo and M. V. Castano, Inorg. Chim. Acta, 24, 227 (1977).

    Google Scholar 

  28. C. J. Popp and R. O. Ragsdale, Inorg. Chem., 7, 1845 (1968).

    Google Scholar 

  29. J. Charalambous, G. Soobramanien, A. Betts and J. Bailey, Inorg. Chim. Acta, 60, 151 (1982).

    Google Scholar 

  30. F. A. Cotton, Advanced Inorganic Chemistry, 3rd Edit., Wiley Eastern, London, 1979.

    Google Scholar 

  31. K. Jorgensen, Absorption Spectra and Chemical Bonding in Complexes, Pergamon Press, Oxford, 1962.

    Google Scholar 

  32. P. W. Ball and A. B. Blake, J. Chem. Soc. (A), 1415 (1969).

  33. B. T. Thaker and P. K. Battacharya, Indian J. Chem., 14, 619 (1976).

    Google Scholar 

  34. R. S. Drago, Physical Methods in Inorganic Chemistry, Affiliated East-West Press PVI, Ltd., New Delhi, 1979.

    Google Scholar 

  35. E. M. Boge, D. P. Freyberg, E. Kokot, G. M. Mockler and E. Sinn, Inorg. Chem., 16, 1655 (1977).

    Google Scholar 

  36. J. Charalambous, M. J. Frazer and F. B. Taylar, J. Chem. Soc. (A), 2787 (1969).

  37. B. J. Hathaway, R. J. Dudley and P. Nicholls, J. Chem. Soc. (A), 1845 (1969).

  38. B. J. Hathaway, I. M. Procter, R. C. Slade and A. A. G. Tomlinson, J. Chem. Soc. (A), 2219 (1969).

  39. B. J. Hathaway in J. N. Bradley and R. D. Gillard (Eds), Essays in Chemistry, Academic Press, 1971, p. 61.

  40. F. K. Kneubuhl, J. Chem. Phys., 33, 1074 (1960).

    Google Scholar 

  41. D. W. Smith, J. Chem. Soc. (A), 3108 (1970).

  42. S. Chandra, K. B. Pandeya and R. P. Singh, J. Indian Chem. Soc., 58, 1097 (1981).

    Google Scholar 

  43. B. J. Hathaway and D. E. Billing, Coord. Chem. Rev., 5, 143 (1970).

    Google Scholar 

  44. G. Krishramoorthy and B. S. Prabhanda, J. Phys. Chem., 84, 639 (1980).

    Google Scholar 

  45. J. Reedijk, Transition Met. Chem., 6, 195 (1981).

    Google Scholar 

  46. H. Langfelderová and O. Hodúr, J. Therm. Anal., 42, 973 (1994).

    Google Scholar 

  47. A. N. Nesmeyanov and N. A. Nesmeyanov, Fundamentals of Organic Chemistry, Mir Publishers, Moscow, 1977, Vol. 3, p. 226.

    Google Scholar 

  48. H. R. Oswald and E. Dubler in H. G. Wiedemann (Ed.), Thermal Analysis, Birkhäuser Verlag, Basel und Stuttgart, Switzerland, 1972, Vol. 2, p. 667.

    Google Scholar 

  49. H. Horowitz and G. Metzger, Anal. Chem., 35, 1464 (1963).

    Google Scholar 

  50. M. L. Dhar and O. Singh, J. Therm. Anal., 37, 259 (1991).

    Google Scholar 

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Masoud, M.S., Haggag, S.S., Ramadan, A.M. et al. Nitrosophenol complexes of transition metal salts. Transition Metal Chemistry 23, 343–348 (1998). https://doi.org/10.1023/A:1006909409145

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