Abstract
The catalytic properties of transition metal oxides (Cr, Ce, and Co) supported on ZrO2 synthesized by various methods, as well as the effect of rhodium on the performance of the Мe х O y /ZrO2 oxide systems in NO reduction with hydrocarbons (methane, propane–butane mixture, and propene) were studied. The acidity of the surface of the catalysts was studied by IR spectroscopy and ammonia temperature-programmed desorption. The adsorption of NO, propene, and their mixture on the Rh–Сr2О3/ZrO2 and Rh–СеO2/ZrO2 catalysts at temperatures of 293–623 K was studied by IR spectroscopy. The adsorption and co-adsorption of the reactants was found to differ significantly depending on the nature of the surface. The activity of the catalysts studied in NO selective catalytic reduction with hydrocarbons is due to the presence of the acidic functional groups on their surface.
Similar content being viewed by others
REFERENCES
Iwamoto, M., Stud. Surf. Sci. Catal., 2002, vol. 130, p. 23.
Fokema, M.D. and Ying, J.Y., Cat. Rev. - Sci. Eng., 2001, vol. 42, nos.1-2, p. 1.
Tana´e, K., Catalysts and Catalytic Processes, Moscow: Mir, 1993.
Fornasiero, P., Rao, G.R., Kaspar, J., L'Erario, F., and Graziani, M., J. Catal., 1998, vol. 175, no.2, p. 269
Pietrogiacomi, D., Sannino, D., Tuti, S., Ciam´elli, P., Indovina, V., and Occhiuzzi, M., Appl. Catal., B, 1998, vol. 21, no.2, p. 141.
Zu´ Yu., L., Ba´ich, N.N., and Orlik, S.N., Book of A´stracts, EuropaCat-, IV., Rimini, 1999, p. 314.
Chuang, S.S.C. and Tan, C.D., J. Catal., 1998, vol. 173, no.1, p. 95.
Kharlanov, A.N., Lunina, E.V., and Lunin, V.V., Zh. Fiz. Khim., 1997, vol. 71, no.9, p. 1672.
Amiridis, M.D., Zhang, T., and Farrauto, R.J., Appl. Catal., B, 1996, vol. 10, p. 203.
Orlik, S.N., Teor. Eksp. Khim., 2001, vol. 37, no.3, p. 133.
Song, X. and Sayari, A., Catal. Rev. - Sci. Eng., 1996, vol. 38, no.3, p. 329.
Ivanov, A.V. and Kustov, L.M., Ross. Khim. Zh., 2000, vol. 44, no.2, p. 21.
Delahay, G., Ensuque, E., Coq, B., and Figueras, F., J. Catal., 1998, vol. 175, no.1, p. 7.
Pietrogiacomi, D., Tuti, S., Campa, M.C., and Indovina, V., Book of A´stracts, 5th Eur. Congr. on Catalysis, Limerik, 2001, p. 48.
Struzhko, V.L., Orlik, S.N., Martsenyuk-Kukharuk, M.G., Tel'´iz, G.M., Ostapyuk, V.A., and Girushtin, Yu.G., Teor. Eksp. Khim., 1996, vol. 32, no.5, p. 306.
Practical Surface Analysis ´y Auger and X-ray Photo-electron Spectroscopy, Briggs, D. and Seah, M.P., Eds., New York: Wiley, 1983, p. 600.
Parvulescu, V.I., Grange, P., and Delmon, B., Catal. Today, 1998, vol. 46, p. 233.
Mironyuk, T.V., Struzhko, V.L., and Orlik, S.N., Teor. Eksp. Khim., 2000, vol. 36, no.5, p. 307.
Hamada, H., Kintaichi, Y., and Ta´ata, M., Chem. Lett., 1991, no. 1, p. 217.
Zhao, Y., Li, W., Zhang, M., and Tao, K., Catal. Commun., 2002, vol. 3, no.6, p. 239.
Orlik, S.N. and Struzhko, V.L., Teor. Eksp. Khim., 1999, vol. 35, no.6, p. 373.
Nefedov, V.I. Rentgenoelektronnaya spektroskopiya khimicheskikh soedinenii (X-ray Electron Spectroscopy of Chemical Compounds), Moscow: Khimiya, 1984.
Hu, Z., Allen, F.M., Wan, C.Z., Heck, R.M., Steger, J.J., Lakis, R.E., and Lyman, C.E., J. Catal., 1998, vol. 174, no.1, p. 13.
Harrison, B., Wyatt, M., and Gough, K.G., Catalysis, 1982, vol. 5, p. 127.
Shelef, M., Chem. Rev., 1995, vol. 95, no.1, p. 209.
Orlik, S.N., Stasevich, V.P., Struzhko, V.L., and Martsenyuk-Kukharuk, M.G., Teor. Eksp. Khim., 1996, vol. 32, no.4, p. 238.
Little, L.H., Infrared Spectra of Adsor´ed Species, New York: Academic, 1966.
Long, R.Q. and Yang, R.T., J. Phys. Chem., 1999, vol. 103, no.12, p. 2232.
Almusaiteer, K.A. and Chuang, S.C., J. Phys. Chem., 2000, vol. 104, no.10, p. 2265.
Sverdlov, L.M., Kovner, M.A., and Krainov, E.P., Kole´atel'nye spektry molekul (Vi´rational Spectra of Molecules), Moscow: Nauka, 1970.
Xin, M., Hwang, I.C., and Woo, S.I., J. Phys. Chem., 1997, vol. 101, no.44, p. 9005.
Kazitsyna, L.A. and Kupletskaya, N.B., Primenenie UF, IK, YaMR i mass-spektroskopii v organicheskoi khimii (Applications of UV, IR, NMR, and Mass Spectrometry), Mosocow: Mosk. Gos. Univ., 1979, p. 240.
Maisuls, S.E., Multiphase Catalysts for Selective Reduction of NO x with Hydrocar´ons, 2000.
Orlik, S.N., Struzhko, V.L., Mironyuk, T.V., and Tel'´iz, G.M., Teor. Eksp. Khim., 2001, vol. 37, no.5, p. 306.
Davydov, A.A., IK-spektroskopiya v khimii poverkhnosti okislov (IR Spectroscopy Applied to the Chemistry of Oxide Surfaces), Novosi´irsk: Nauka, 1984.
Matyshak, V.A. and Krylov, O.V., Catal. Today, 1995, vol. 25, p. 1.
Hopstaken, M.J.P. and Niemantsverdriet, J.W., J. Phys. Chem., 2000, vol. 104, no.14, p. 3058.
Daturi, M., Finnocchio, E., Binet, C., Lavalley, J.-C., Fally, F., Perrichon, V., Vidal, H., Hickey, N., and Kaspar, J., J. Phys. Chem., 2000, vol. 104, no.39, p. 9186.
Fornasiero, P., Ranga Rao, G., Kaspar, J., L'Erario, F.L., and Graziani, M., J. Catal., 1998, vol. 175, no.2, p. 269.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Orlik, S.N., Struzhko, V.L., Mironyuk, T.V. et al. Role of Bifunctionality of ZrO2-Based Oxide Systems in NO Reduction with Lower Hydrocarbons. Kinetics and Catalysis 44, 682–691 (2003). https://doi.org/10.1023/A:1026154425081
Issue Date:
DOI: https://doi.org/10.1023/A:1026154425081