Abstract
The incorrectness of solution of a torsional-rotational equation for asymmetric nonrigid molecules in the system of internal axes is shown; this incorrectness is caused by the broken interrelationship between the torsional quantum number τ and the parity of the rotational quantum number K.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
P. R. Bunker, Molecular Symmetry and Spectroscopy [Russian translation], Moscow (1981).
C. C. Lin and J. D. Swalen, Rev. Mod. Phys., 31, 841–892 (1959).
J.-M. Flaud, C. Camy-Peyret, J. W. C. Johns, and B. Carli, Chem. Phys., 91, 1504–1510 (1989).
R. H. Hunt, R. A. Leacock, C. W. Peters, and K. T. Hecht, J. Chem. Phys., 42, 1931–1946 (1965).
J. K. Hale, Oscillation in Nonlinear Systems [Russian translation], Moscow (1981).
J. M. Fernandez-Sanchez, A. G. Valdenebro, and S. Montero, J. Chem. Phys., 91, 3327–3334 (1989).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Shundalov, M.B., Pitsevich, G.A. Interrelationship of the Torsional and Rotational States of Asymmetric Nonrigid Molecules. Journal of Applied Spectroscopy 68, 911–916 (2001). https://doi.org/10.1023/A:1014378426956
Issue Date:
DOI: https://doi.org/10.1023/A:1014378426956