Synthesis of (azidomethyl)phenylboronic acids
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- Fedorov, A.Y., Shchepalov, A.A., Bol"shakov, A.V. et al. Russian Chemical Bulletin (2004) 53: 370. doi:10.1023/B:RUCB.0000030813.05424.1f
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The synthesis of 2-, 3-, and 4-(azidomethyl)phenylboronic acids was carried out. The geometric and electronic structures were studied by quantum-chemical methods. The suggestion is made that there are weak intramolecular interactions between the boron atom and the nitrene nitrogen atom of the azido group.