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Synthesis of acetone oxime through acetone ammoximation over TS-1

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Abstract

The ammoximation of acetone to acetone oxime with 30 wt.% hydrogen peroxide over TS-1 has been studied. The conversion of acetone and the selectivity to acetone oxime can reach 99% and 94%, respectively. The by-products are the corresponding hydrazone, imine and small amounts of unidentified compounds. The influence of various parameters such as solvent, temperature, amounts of catalyst and the NH3 to acetone molar ratio were investigated.

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Authors and Affiliations

  1. School of Chemical Engineering &Technology, Tianjin University, Tianjin, 300072, P. R. China

    Xinhua Liang, Zhentao Mi, Yaquan Wang, Li Wang & Xiangwen Zhang

Authors
  1. Xinhua Liang
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  2. Zhentao Mi
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  3. Yaquan Wang
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  4. Li Wang
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  5. Xiangwen Zhang
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Correspondence to Zhentao Mi.

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Liang, X., Mi, Z., Wang, Y. et al. Synthesis of acetone oxime through acetone ammoximation over TS-1. Reaction Kinetics and Catalysis Letters 82, 333–337 (2004). https://doi.org/10.1023/B:REAC.0000034845.65961.3e

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  • DOI: https://doi.org/10.1023/B:REAC.0000034845.65961.3e

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