Journal of Radioanalytical and Nuclear Chemistry

, Volume 261, Issue 3, pp 609–617

Evaluation of a single collector, double focusing sector field inductively coupled plasma mass spectrometer for the determination of U and Pu concentrations and isotopic compositions at trace level

  • N. Baglan
  • P. Hemet
  • F. Pointurier
  • R. Chiappini
Article

DOI: 10.1023/B:JRNC.0000037103.25378.42

Cite this article as:
Baglan, N., Hemet, P., Pointurier, F. et al. Journal of Radioanalytical and Nuclear Chemistry (2004) 261: 609. doi:10.1023/B:JRNC.0000037103.25378.42

Abstract

This work explores the performance of the “Axiom”, a double focusing sector field ICP-MS (ICP-SFMS) in the determination of actinide concentration and isotopic ratio at trace level. On the actinide mass range the performances observed are characterized by high sensitivity, around 2.8·106 cps·µg−1·l, and low background, below 0.3 cps. Therefore, the absolute instrumental detection limit is approximately 0.05 fg for Pu isotopes. Furthermore, the 235U/238U ratio for a 0.5 µg·l−1 U500 isotopic standard could now be measured using the ICP-SFMS with a relative standard deviation less than 0.1%. Moreover, the accuracy of the measured ratio was demonstrated at low concentration with the target value remaining within experimental uncertainty limits.

Copyright information

© Kluwer Academic Publisher/Akadémiai Kiadó 2004

Authors and Affiliations

  • N. Baglan
    • 1
  • P. Hemet
    • 1
  • F. Pointurier
    • 1
  • R. Chiappini
    • 1
  1. 1.CEA/DIF/DASE/SRCE - BP 12 -France