A General Method for Preparation of PVP-Stabilized Noble Metal Nanoparticles in Room Temperature Ionic Liquids
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- Mu, X., Evans, D.G. & Kou, Y. Catalysis Letters (2004) 97: 151. doi:10.1023/B:CATL.0000038577.18441.bf
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Platinum, palladium and rhodium nanoparticles stabilized by poly(N-vinyl-2-pyrrolidone) (PVP) can be synthesized by ethanolic reduction of the corresponding metal halide salts and when immobilized in an ionic liquid, 1-n-butyl-3-methylimidazolium hexafluorophosphate ([BMI][PF6]), are very effective olefin hydrogenation catalysts which are capable of being recycled by a simple decantation procedure without loss of activity.