Journal of Materials Science: Materials in Medicine

, Volume 14, Issue 7, pp 575–581

A novel acrylic copolymer for a poly(alkenoate) glass-ionomer cement


DOI: 10.1023/A:1024062705439

Cite this article as:
Deb, S., Shah, P., Vazquez, B. et al. Journal of Materials Science: Materials in Medicine (2003) 14: 575. doi:10.1023/A:1024062705439


The interest in the clinical use of polyalkenoate cements stems mainly from their behavior as bioactive adhesive materials with therapeutic action. Glass-ionomer cements set by an acid-base reaction between a degradable glass and a poly(alkenoic acid) and the therapeutic action is related to the release of fluoride ions which are present in the hardened cement that show a sustained release over years, responsible for caries inhibition in teeth. Conventional glass-ionomers, however, suffer from some disadvantages such as short working time, initial moisture sensitivity and prone to desiccation after setting and are generally brittle. In the present study, a poly(alkenoic acid) copolymer was synthesized based on acrylic acid and 2-hydroxyethylmethacrylate (HEMA) using azobisisobutyronitrile as the initiator and characterized. The acid–base reaction was carried out by reacting aqueous solutions of the new copolymer (40 and 60%) with a commercial aluminofluorosilicate glasses as used in conventional glass-ionomer cements. The results showed that the copolymer of HEMA and acrylic acid was a viable poly(alkenoic) acid for formation of glass-ionomer cements.

Copyright information

© Kluwer Academic Publishers 2003

Authors and Affiliations

  1. 1.Department of Biomaterials, Floor 17 Guy's TowerGKT Dental Institute, King's College London, London BridgeLondonUK
  2. 2.Instituto de Ciencia y Tecnologia de PolimerosMadridSpain