Catalysis Letters

, Volume 56, Issue 1, pp 7–10

Structure sensitivity of CO oxidation over model Au/TiO22 catalysts

Authors

  • M. Valden
    • Department of PhysicsTampere University of Technology
  • S. Pak
    • Department of ChemistryTexas A&M University
  • X. Lai
    • Department of ChemistryTexas A&M University
  • D.W. Goodman
    • Department of ChemistryTexas A&M University
Article

DOI: 10.1023/A:1019028205985

Cite this article as:
Valden, M., Pak, S., Lai, X. et al. Catalysis Letters (1998) 56: 7. doi:10.1023/A:1019028205985

Abstract

Model catalysts of Au clusters supported on TiO2 thin films were prepared under ultra-high vacuum (UHV) conditions with average metal cluster sizes that varied from ~2.5 to ~6.0 nm. The reactivities of these Au/TiO2 catalysts were measured for CO oxidation at a total pressure of 40 Torr in a reactor contiguous to the surface analysis chamber. Catalyst structure and composition were monitored with Auger electron spectroscopy (AES) and scanning tunneling microscopy and spectroscopy (STM/STS). The apparent activation energy for the reaction between 350 and 450 K varied from 1.7 to 5 kcal/mol as the Au coverage was increased from 0.25 to 5 monolayers, corresponding to average cluster diameters of 2.5–6.0 nm. The specific rates of reaction ((product molecules) × (surface site)-1 × s-1 were dependent on the Au cluster size with a maximum occurring at 3.2 nm suggesting that CO oxidation over Au/TiO2(001)/Mo(100) is structure sensitive.

gold catalysisCO oxidationgold/titaniastructure/activity relationships

Copyright information

© Kluwer Academic Publishers 1998