Journal of Materials Science

, Volume 36, Issue 17, pp 4201–4207

Preparation of a visible-light-active TiO2 photocatalyst by RF plasma treatment

Authors

    • Department of Chemistry and Environmental TechnologyKinki University
  • M. Miyoshi
    • Department of Chemistry and Environmental TechnologyKinki University
  • M. Ando
    • Ecodevice Co. Ltd.
  • S. Sugihara
    • Ecodevice Co. Ltd.
  • Y. Iriyama
    • Division of Interdisciplinary SciencesYamanashi University
Article

DOI: 10.1023/A:1017929207882

Cite this article as:
Ihara, T., Miyoshi, M., Ando, M. et al. Journal of Materials Science (2001) 36: 4201. doi:10.1023/A:1017929207882

Abstract

In order to realize a visible (vis)-light-active TiO2 photocatalyst, reduction treatment using low-temperature hydrogen plasma with elevated temperatures was applied on anatase TiO2 powder of ST-01 without causing a phase transition to rutile. According to plasma-heat treatment, oxygen was evacuated from ST-01 particles and the colored ST-01, ivory to beige, was obtained. XPS results showed non-stoichiometric, expressed as TiO2−x} and x was increased with the increase of treating time. Plasma-heat treated ST-01 showed new ESR signal at g = 2.003 assigned to electrons trapped at the oxygen-defect site. This signal was strengthened when vis-light illumination was applied. Results of vis-light activity tests, evaluated by photocatalytic oxidation of benzoic acid in liquid phase and 2-propanol in gas phase using vis-light illumination (>406 nm), showed excellent activity while low ST-01 showed almost no activity on both tests.

Copyright information

© Kluwer Academic Publishers 2001