Catalysis Letters

, Volume 79, Issue 1, pp 21–25

Catalytic Decomposition of Hydrazine over Supported Molybdenum Nitride Catalysts in a Monopropellant Thruster

  • Xiaowei Chen
  • Tao Zhang
  • Liangen Xia
  • Tao Li
  • Mingyuan Zheng
  • Zili Wu
  • Xiaodong Wang
  • Zhaobin Wei
  • Qin Xin
  • Can Li
Article

DOI: 10.1023/A:1015343922044

Cite this article as:
Chen, X., Zhang, T., Xia, L. et al. Catalysis Letters (2002) 79: 21. doi:10.1023/A:1015343922044

Abstract

The catalytic decomposition of hydrazine over a series of MoNx/γ-Al2O3 catalysts with different Mo loadings was investigated in a monopropellant thruster (10 N). When the Mo loading is equal to or higher than the monolayer coverage of MoO3 on γ-Al2O3, the catalytic performance of the supported molybdenum nitride catalyst is close to that of the conventionally used Ir/γ-Al2O3 catalyst. The MoNx/γ-Al2O3 catalyst with a loading of about 23 wt% Mo (1.5 monolayers) shows the highest activity for hydrazine decomposition. There is an activation process for the MoNx/γ-Al2O3 catalysts at the early stage of hydrazine decomposition, which is probably due to the reduction of the oxide layer formed in the passivation procedure.

hydrazine decompositionsupported molybdenum nitridepassivationmonopropellant thruster

Copyright information

© Plenum Publishing Corporation 2002

Authors and Affiliations

  • Xiaowei Chen
    • 1
  • Tao Zhang
    • 1
  • Liangen Xia
    • 1
  • Tao Li
    • 1
  • Mingyuan Zheng
    • 1
  • Zili Wu
    • 1
  • Xiaodong Wang
    • 1
  • Zhaobin Wei
    • 1
  • Qin Xin
    • 1
  • Can Li
    • 1
  1. 1.State Key Laboratory of Catalysis, Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalianPR China