Journal of Inorganic and Organometallic Polymers

, Volume 11, Issue 3, pp 123–154

Polyhedral Oligomeric Silsesquioxane (POSS) Polymers and Copolymers: A Review

Authors

  • Guizhi Li
    • Department of ChemistryMississippi State University
  • Lichang Wang
    • Department of ChemistryMississippi State University
  • Hanli Ni
    • Department of ChemistryMississippi State University
    • Department of ChemistryMississippi State University
Article

DOI: 10.1023/A:1015287910502

Cite this article as:
Li, G., Wang, L., Ni, H. et al. Journal of Inorganic and Organometallic Polymers (2001) 11: 123. doi:10.1023/A:1015287910502

Abstract

This review describes the synthesis and properties of homopolymers and copolymers of monomers containing inorganic–organic hybrid polyhedral oligomeric silsesquioxane (POSS) structures. Monomers, such as styryl-POSS, methacrylate-POSS, norbornyl-POSS, vinyl-POSS, epoxy-POSS, and siloxane-POSS, are included. Both monofunctional and multifunctional monomers are included. Thermoplastic and thermoset systems are considered. Thermal, rheological, and dynamic mechanical properties are described. The synthesis of POSS macromers (monomers) is briefly described. POSS chemicals have been used to prepare nanosized designed novel composites with a variety of potential applications. This review, covering 111 references, is descriptive and not designed to be totally comprehensive. However, the major existing reviews of certain subtopics are noted, allowing the reader to gain a general introduction while providing the information to permit more comprehensive coverage.

polyhedral oligomeric silsesquioxane (POSS) polymersPOSS macromersthermoplasticsthermosetsthermal and mechanical properties
Download to read the full article text

Copyright information

© Plenum Publishing Corporation 2001