Journal of Cluster Science

, Volume 13, Issue 1, pp 119–136

Syntheses, Structures, Bonding, and Optical Properties of Trinuclear Cluster Iodides: M33-I)2(μ-dppm)3·I (M=Cu, Ag), dppm=bis(diphenylphosphino)methane)

  • Wen-Bo Zhou
  • Zhen-Chao Dong
  • Jun-Ling Song
  • Hui-Yi Zeng
  • Rong Cao
  • Guo-Cong Guo
  • Jin-Shun Huang
  • Jun Li
Article

DOI: 10.1023/A:1015195130685

Cite this article as:
Zhou, W., Dong, Z., Song, J. et al. Journal of Cluster Science (2002) 13: 119. doi:10.1023/A:1015195130685

Abstract

The title compounds were obtained from the reactions of copper or silver monohalides with the bidentate bis(diphenylphosphino)methane (dppm) ligand at room temperature in a mixed solvent. Single-crystal X-ray diffraction analyses indicate that both compounds crystallize in a monoclinic system but in different space groups. The structures are characterized by a trinuclear [M3I2(dppm)3]+ cation with a trigonal-bipyramid [M3(μ3-I)2] core. In agreement with the geometric characteristics of the M3 triangles, 31P NMR spectra exhibit a single peak for the [Cu3] cluster but a double-peak for the [Ag3] cluster. Preliminary optical studies by UV/Vis and emission techniques show major absorption shoulders at ∼286 nm for Cu3I2(dppm)3·I and ∼254 nm for Ag3I2(dppm)3·I, but no luminescence in the non-degassed MeCN solution at 298 K. The structures, bonding, electronic excitations and emissions are discussed based on relativistic density functional theory calculations.

trinuclear clustersCuAgdppmhalidesoptical propertieselectronic structures

Copyright information

© Plenum Publishing Corporation 2002

Authors and Affiliations

  • Wen-Bo Zhou
    • 1
  • Zhen-Chao Dong
    • 1
  • Jun-Ling Song
    • 1
  • Hui-Yi Zeng
    • 1
  • Rong Cao
    • 1
  • Guo-Cong Guo
    • 1
  • Jin-Shun Huang
    • 1
  • Jun Li
    • 3
  1. 1.State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou, FujianPeople's Republic of China
  2. 2.National Institute for Materials ScienceTsukuba, IbarakiJapan
  3. 3.Department of ChemistryThe Ohio State UniversityColumbusUSA