, Volume 248, Issue 1, pp 239-246

Detection and quantification capabilities for 85Kr with the NIST low-level gas counting system: Impacts of instrumental and environmental backgrounds

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Abstract

Among the most important, conservative geochemical tracers are the long-lived isotopes of krypton, 81Kr and 85Kr. Following a brief review of the metrology and applications of these radionuclides, we focus on the low-level measurement of the 10.8 year fission product 85Kr, in connection with its use for studying atmospheric transport and short term (decadal) atmosphere-ocean exchange and mixing. Special challenges for the study of 85Kr in the environment are: (1) reducing detection/quantification limits to mBq levels, to minimize the need for costly (large) atmospheric and marine samples, where current levels are ca. 1.4 Bq·m-3 (northern troposphere) and 0.08 mBq·kg-1 (surface ocean water); and (2) designing a protocol that accounts for the influence of both instrumental and environmental backgrounds and their variability. The capability of the NIST enhanced low-level gas counting system to meet these challenges was demonstrated theoretically and experimentally, showing that ambient 85Kr can be quantified in just 1.5 l air or 25 l seawater with 2000 min paired counting periods.