Journal of Materials Science

, Volume 34, Issue 16, pp 3859–3866

Preparation, structure and properties of uniaxially oriented polyethylene-silver nanocomposites


  • Y. Dirix
    • Department of MaterialsETH Zürich
  • C. Bastiaansen
    • Department of MaterialsETH Zürich
  • W. Caseri
    • Department of MaterialsETH Zürich
  • P. Smith
    • Department of MaterialsETH Zürich

DOI: 10.1023/A:1004614604641

Cite this article as:
Dirix, Y., Bastiaansen, C., Caseri, W. et al. Journal of Materials Science (1999) 34: 3859. doi:10.1023/A:1004614604641


Uniaxially oriented composites of high-density polyethylene and silver nanoparticles were prepared using solution-casting, melt-extrusion and solid-state drawing techniques. The absorption spectrum in the visible wavelength range of the drawn nanocomposites was observed to strongly depend on the polarisation direction of the incident light. For instance, the nanocomposites appear bright yellow or red when the vibration direction of linearly polarised light is perpendicular or parallel, respectively, to the drawing axis. The optical anisotropy of the drawn nanocomposites originates from uniaxially oriented, pearl-necklace type of arrays of nanoparticles of high aspect ratios. The absorption spectrum of the nanocomposites can be shifted to higher wavelengths using appropriate annealing procedures. The annealing results in an increased size of the primary silver particles, due to Ostwald ripening, and consequently a range of polarisation-dependent colours can be generated in the drawn nanocomposites.

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© Kluwer Academic Publishers 1999