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Kinetics and Mechanism of in situ Simultaneous Formation of Metal Nanoparticles in Stabilizing Polymer Matrix

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Abstract

The kinetic peculiarities of the thermal transformations of unsaturated metal carboxylates (transition metal acrylates and maleates as well as their cocrystallites) and properties of metal-polymer nanocomposites formed have been studied. The composition and structure of metal-containing precursors and the products of the thermolysis were identified by X-ray analysis, optical and electron microscopy, magnetic measurements, EXAFS, IR and mass spectroscopy. The thermal transformations of metal-containing monomers studied are the complex process including dehydration, solid phase polymerization, and thermolysis process which proceed at varied temperature ranges. At 200–300°C the rate of thermal decay can be described by first-order equations. The products of decompositions are nanometer-sized particles of metal or its oxides with a narrow size distribution (the mean particle diameter of 5–10nm) stabilized by the polymer matrix.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, 142432, Russian Federation

    Anatolii D. Pomogailo, Gulzhian I. Dzhardimalieva & Aleksander S. Rozenberg

  2. Departamento de Química, Universitat Autonoma de Barcelona, 08193 Bellaterra, Barcelona, Spain

    Dmitri N. Muraviev

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Pomogailo, A.D., Dzhardimalieva, G.I., Rozenberg, A.S. et al. Kinetics and Mechanism of in situ Simultaneous Formation of Metal Nanoparticles in Stabilizing Polymer Matrix. Journal of Nanoparticle Research 5, 497–519 (2003). https://doi.org/10.1023/B:NANO.0000006091.92638.a5

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