Abstract
Removal of methylene blue(MB) from aqueous solution by a new polyoxometalate-based metal-organic framework composite(POM@MOF) was systematically explored in batch tests. The chemical structure and surface properties of the composite were characterized by means of FTIR, XRD, EDS, N2 adsorption-desorption isotherms and zeta potential measurements. The results showed that MB adsorption onto H6P2Mo15W3O62@Cu3(BTC)2 highly depended on initial solution pH, which was mainly related to the electrostatic attraction between negatively charged composite surface and positively charged MB molecules. Thus, the improved adsorption performance of H6P2Mo15W3O62@Cu3(BTC)2 can be attributed to the modification of H6P2Mo15W3O62 resulting in its higher electronegative charge than Cu3(BTC)2. The thermodynamic parameters indicated that the adsorption was spontaneous and exothermic process. The isotherm obtained fitted the Langmuir model and the maximum adsorption capacity of the composite at 30 ºC was 77.22 mg/g. All the results illustrated that H6P2Mo15W3O62@Cu3(BTC)2 composite can effectively and selectively remove cationic organic pollutants, represented by MB, implying the promising application of designing a novel adsorbent polyoxometalate-based metal-organic frameworks in treatment of dye wastewater.
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Zhao G., Liu L., Li J., Liu Q., J. Alloy Compd., 2016, 664, 169
Mei J., Zhang L., Niu Y., Mater. Res. Bull., 2015, 70, 82
Fan Y., Liu H., Zhang Y., Chen Y., J. Hazard. Mater., 2015, 283, 321
Madrakian T., Afkhami A., Mahmood-Kashani H., Ahmadi M., J. Iran. Chem. Soc., 2013, 10, 481
Yao L., Zhang L., Dong Z., Chou S., Dong Z., J. Hazard. Mater., 2016, 301, 462
Gomes R. F., Neto de Azevedo A. C., Pereira A. G. B., Muniz E. C., Fajardo A. R., Rodrigues F. H. A., J. Colloid Interf. Sci., 2015, 454, 200
Sheng S., Han Y., Wang B., Zhao C., Yang F., Zhao M. J., Xie Y. B., Li J. R., J. Solid State Chem., 2016, 233, 143
Salima A., Ounissa K. S., Lynda M., Mohamed B., Procedia Engineering, 2012, 33, 38
Yuan W., Yuan P., Liu D., Yu W. B., Deng L. L., Chen F. R., J. Colloid Interf. Sci., 2015, 462, 191
Liu D., Yuan W., Yuan P., Yu W. B., Tan D. Y., Liu H. M., He H. P., Appl. Surf. Sci., 2013, 282, 838
Wong K. T., Eu N. C., Ibrahim S., Kim H., Yoon Y., Jang M., J. Clean. Prod., 2015, 115, 337
Yang S. T., Chen S., Chang Y. L., Cao A., Liu Y., Wang H., J. Colloid Interface Sci., 2011, 359, 24
Xie Y., Yan B., Xu H., Chen J., Liu Q. X., Deng Y. H., Zeng H. B., ACS Appl. Mater. Interfaces, 2014, 6, 8845
Zhang C., Li P., Huang W., Cao B., Chem. Eng. Res. Des., 2016, 109, 76
Yi F., Zhu W., Dang S., Li J. P., Wu D., Chem. Commun., 2015, 51, 3336
Hu X., Lu Y., Dai F., Liu C. G., Liu Y. Q., Micropor. Mesopor. Mater., 2013, 170, 36
Yang H., Liu T., Cao M., Li H., Gao S., Chem. Commun., 2010, 46, 2429
Wee L. H., Bajpe S. R., Janssens N., Hermans I., Houthoofd K., Chem. Commun., 2010, 46, 8186
Park D. R., Song J. H., Lee S. H., Song S. H., Kim H., Jung J. C., Song I. K., Appl. Catal. A: Gen., 2008, 349, 222
Klaus S., Tobias K., Stefan. K., Microporous Mesoporous Mater., 2004, 73, 81
Bielanski A., Lubanska A., J. Mol. Catal. A: Chem., 2004, 224, 179
Sun C. Y., Liu S. X., Liang D. D., Shao K. Z., Ren Y. H., Su Z. M., J. Am. Chem. Soc., 2009, 131, 1883
Uemura T., Kadowaki Y., Kim C. R., Fukushima T., Hiramatsu D., Kitagawa S., Chem. Mater., 2011, 23, 1736
Ke F., Qiu L., Zhu J., Peng F. M., Jiang X., Xie A. J., Shen Y. H., Zhu J. F., J. Hazard. Mater., 2011, 196, 36
Yan A. X., Yao S., Wang E. B., Zhang Z. M., Lu Y., Chen W. L., Wang E. B., Chem. Eur. J., 2014, 20, 6927
Lin S., Song Z., Che G., Ren A., Li P., Liu C. B., Zhang J. S., Micropor. Mesopor. Mater., 2014, 193, 27
Li L., Chen L., Shi H., Chen X., Lin W., J. Environ. Chem. Eng., 2016, 4, 1451
Yang Y., Zhao Y., Sun S., Zhang X. Y., Duan L. F, Ge X., Lü W., Mater. Res. Bull., 2016, 73, 401
Liu F., Zou H., Huo Y., Liu H. B., Peng J. B., Chen Y. W., Lu F. H., Huo Y. P., Chem. Eng. J., 2016, 287, 410
Wang H. L., Zhao Y., Ma L. K., Fan P. H., Xu C. B., Jiao C. L., Lin A. J., Chem. J. Chinese Universities, 2016, 37(2), 335
Gong W. P., Tian C. Q., Du X. G., Yang S. J., Chem. J. Chinese Universities, 2016, 37(9), 1596
Chen X., Lv S., Liu S., Zhang P., Zhang A., Sun J., Sep. Sci. Technol., 2012, 47, 147
Chandra T. S., Mudliar S.N., Vidyashankar S., Mukherji S., Sarada R., Krishnamurthi K., Chauhan V. S., Bioresour. Technol., 2015, 184, 395
Cherifi H., Fatiha B., Salah H., Appl. Surf. Sci., 2013, 282, 52
Shah B.A., Shah A.V., Patel H. D., Int. J. Environ. Waste Manag., 2010, 7, 192
Woolard C., Strong J., Erasmus C., Appl. Geochem., 2002, 17, 1159
Xie J., Li C., Chi L., Wu D., Fuel, 2013, 103, 480
Zhang F., Song W., Lan J., Appl. Surf. Sci., 2015, 326, 195
Mashhadi S., Sohrabi R., Gupta V. K., J. Mol. Liq., 2016, 215, 144
Li X. X., Gong W. P., Yang S. J., Appl. Surf. Sci., 2016, 362, 517
Salem A. M., Ahmed M. A., El-Shahat M. F., J. Mol. Liq., 2016, 219, 780
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Supported by the National Natural Science Foundation of China(No.21171053), the Natural Science Foundation of Hubei Province, China(No.2014CFA131), the Graduate Student Innovation Research Fund of Hubei Normal University, China (No.20160107).
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Liu, X., Luo, J., Chen, X. et al. Selective adsorption performance of H6P2Mo15W3O62-based Cu3(BTC)2 composite in treatment of simulated cationic dye wastewater. Chem. Res. Chin. Univ. 33, 268–273 (2017). https://doi.org/10.1007/s40242-017-6350-4
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DOI: https://doi.org/10.1007/s40242-017-6350-4