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Aldol reactions catalyzed by proline functionalized polyacrylonitrile fiber

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Abstract

A proline functionalized fiber catalyst was employed for aldol reactions in water. In the presence of the fiber catalyst, the aldol reactions proceeded smoothly at 40 °C and the products were obtained in excellent yields which were higher than those obtained for the reactions catalyzed by L-proline or trans-4-hydroxy-L-proline. This newly developed fiber catalyst is applicable to the reactions of a wide range of aromatic aldehydes and exhibits excellent reusability(up to 6 times) without any additional treatment.

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Authors and Affiliations

  1. Department of Chemistry, School of Sciences, Tianjin University, Tianjin, 300072, P. R. China

    Jia Xiao, Guo-wei Li & Wen-qin Zhang

Authors
  1. Jia Xiao
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  2. Guo-wei Li
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  3. Wen-qin Zhang
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Correspondence to Wen-qin Zhang.

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Supported by the National Natural Science Foundation of China(No.20834002).

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Xiao, J., Li, Gw. & Zhang, Wq. Aldol reactions catalyzed by proline functionalized polyacrylonitrile fiber. Chem. Res. Chin. Univ. 29, 256–262 (2013). https://doi.org/10.1007/s40242-013-2236-2

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  • DOI: https://doi.org/10.1007/s40242-013-2236-2

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