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Construction of two chiral bilayer coordination polymers based on 2-(pyridine-3-yl)-1H-4,5-imidazoledicarboxylate ligand

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Abstract

Two novel isomorphic coordination polymers [Zn(HPyImDC)H2O](1) and [Co(HPyImDC)H2O](2) were synthesized from 2-(pyridine-3-yl)-1H-4,5-imidazoledicarboxylic acid(H3PyImDC) under hydrothermal conditions. Both the compounds crystallized in P212121 chiral space group, possessing left-hand helical chains and right-hand helical chains. Two types of helical chains connected with each other to form an interesting 2D bilayer structure which extended to a 3D supermolecular structure via the hydrogen-bonding interactions. Topology analysis shows that H3PyImDC ligand and metal center can be regarded as 3-connected T-shaped nodes, thus leading to a (3,3)-connected network with vertex symbol of (82·10).

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Authors and Affiliations

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, P. R. China

    Xiao-ying Zhou, Da Xu, Guang-hua Li & Li-rong Zhang

  2. Faculty of Chemistry and Material Science, Langfang Teachers College, Langfang, 065000, P. R. China

    Xue-min Jing

  3. College of Science, Changchun Institute of Technology, Changchun, 130012, P. R. China

    Wei-wei Yan

Authors
  1. Xiao-ying Zhou
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  2. Xue-min Jing
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  3. Da Xu
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  4. Wei-wei Yan
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  5. Guang-hua Li
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  6. Li-rong Zhang
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Correspondence to Li-rong Zhang.

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Supported by the National Natural Science Foundation of China(No.20701015).

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Zhou, Xy., Jing, Xm., Xu, D. et al. Construction of two chiral bilayer coordination polymers based on 2-(pyridine-3-yl)-1H-4,5-imidazoledicarboxylate ligand. Chem. Res. Chin. Univ. 29, 6–9 (2013). https://doi.org/10.1007/s40242-013-2194-8

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  • DOI: https://doi.org/10.1007/s40242-013-2194-8

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