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Palladium(II) Complex of 4-Pyridylselenolate Ligand: An Efficient Catalyst for Aminocarbonylation of Aryl and Hetero Aryl Iodides with Primary Amines

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Abstract

The present work describes the synthesis of palladium(II) complex with non-chelating 4-pyridylselenolate ligand as [PdCl(4-SeC5H4N)(PPh3)2]. The catalyst was found to be active for aminocarbonylation reaction of aryl and hetero aryl iodides with primary amines using carbon monoxide a simple and efficient C1 source. The catalytic system was optimized with respect to various reaction parameters to give excellent yield of desired products. The milder reaction conditions and wild functional groups tolerance enhance its practical applicability.

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Authors and Affiliations

  1. Department of Chemistry, Institute of Chemical Technology, Mumbai, India

    Sujit P. Chavan & Bhalchandra M. Bhanage

  2. Chemistry Division, Bhabha Atomic Research Centre, Mumbai, India

    Sandip Dey & Vimal K. Jain

Authors
  1. Sujit P. Chavan
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  2. Sandip Dey
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  3. Vimal K. Jain
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  4. Bhalchandra M. Bhanage
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Correspondence to Bhalchandra M. Bhanage.

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Chavan, S.P., Dey, S., Jain, V.K. et al. Palladium(II) Complex of 4-Pyridylselenolate Ligand: An Efficient Catalyst for Aminocarbonylation of Aryl and Hetero Aryl Iodides with Primary Amines. Proc. Natl. Acad. Sci., India, Sect. A Phys. Sci. 86, 581–587 (2016). https://doi.org/10.1007/s40010-016-0291-z

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  • DOI: https://doi.org/10.1007/s40010-016-0291-z

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