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Direct synthesis of CdS nanoparticles via simple one-pot calcination of new two-dimensional Cd(II) coordination polymer

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Abstract

Assembly of quinoxaline with Cd(II) in the presence of SCN− anion produces a new coordination polymer [Cd(Quinoxaline)(SCN)2(CH3CN)] n [Cd(Quinoxaline)2(SCN)2] n (1) and is characterized by IR, 1H NMR and 13C NMR spectroscopy. The single-crystal X-ray data of compound 1 show that this coordination polymer grows in two-dimensional supramolecular structure. In this polymer, the organic ligand chelate through its one nitrogen atom to cadmium(II) atom and thiocyanate anion acts as a bridge to two cadmium(II) atom in the chains. Also, nanoscale of CdS has been synthesized by calcination at 400, 500 and 600 °C under air atmosphere and characterized by scanning electron microscopy, X-ray powder diffraction and energy-dispersive X-ray. The thermal stability of compound 1 was studied by thermal gravimetric and differential thermal analyses.

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Acknowledgements

This work is funded by the Grant 2011-0014246 of the National Research Foundation of Korea. This work was supported by the Payame Noor, Tarbiat Modares, Messina and Isfahan Universities.

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Authors and Affiliations

  1. Department of Chemistry, Payame Noor University, Abhar, Zanjan, Islamic Republic of Iran

    Akram Piri & Fatemeh Molaei

  2. Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14115-175, Tehran, Islamic Republic of Iran

    Lida Hashemi & Ali Morsali

  3. Dipartimento di Chimica Inorganica, Università di Messina, Vill. S. Agata, Salita Sperone 31, 98166, Messina, Italy

    Giuseppe Bruno

  4. Department of Chemistry, University of Isfahan, Isfahan, 81746-73441, Islamic Republic of Iran

    Hadi Amiri Rudbari

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  1. Akram Piri
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  2. Fatemeh Molaei
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  3. Lida Hashemi
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  4. Ali Morsali
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  5. Giuseppe Bruno
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Correspondence to Ali Morsali.

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Piri, A., Molaei, F., Hashemi, L. et al. Direct synthesis of CdS nanoparticles via simple one-pot calcination of new two-dimensional Cd(II) coordination polymer. J IRAN CHEM SOC 14, 1541–1548 (2017). https://doi.org/10.1007/s13738-017-1095-z

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  • DOI: https://doi.org/10.1007/s13738-017-1095-z

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