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Recent advances in catalysts immobilized on magnetic nanoparticles

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Abstract

Unsupported nanoparticles are often less stable, and usually coagulation is unavoidable during the catalytic reactions. To generate stable nanoparticles with good activity, stabilizing the surface is required. Protection has been performed by the addition of polymers or long-chain alkyl surfactants with polar functional groups that attached to the nanoparticle surface via covalent or electrostatic interactions. Alternatively, nanoparticles have been immobilized or grafted onto inorganic supports to improve their stabilization and recycling ability. In this article, the green catalytic processes and recent advances in organic transformations catalyzed by magnetically retrievable catalysts are reviewed. Prior to this, methods for the synthesis of catalysts immobilized on magnetic nanoparticles are addressed briefly.

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References

  1. C.J. Murphy, J. Mater. Chem. 18, 2173–2176 (2008)

    Article  CAS  Google Scholar 

  2. V.F. Puntes, K.M. Krishnan, A.P. Alivisatos, Science 291, 2115–2117 (2001)

    Article  CAS  Google Scholar 

  3. H.G. Yang, C.H. Sun, S.Z. Qiao, J. Zou, G. Liu, S.C. Smith, H.M. Cheng, G.Q. Lu, Nature 453, 638–641 (2008)

    Article  CAS  Google Scholar 

  4. G.M. Whitesides, B. Grzybowski, Science 295, 2418–2421 (2002)

    Article  CAS  Google Scholar 

  5. G.A. Ozin, Adv. Mater. 4, 612–649 (1992)

    Article  CAS  Google Scholar 

  6. Y. Gao, Z. Tang, Small 15, 2133–2146 (2011)

    Article  Google Scholar 

  7. G.A. Somorjai, J.Y. Park, Angew. Chem. Int. Ed. 47, 9212–9228 (2008)

    Article  CAS  Google Scholar 

  8. C.N.R. Rao, A. Muller, A.K. Cheetham, The Chemistry of Nanomaterials: Synthesis and Applications, vol. 1 (Wiley-VCH, Weinheim, 2004)

    Book  Google Scholar 

  9. Y.W. Jun, J.W. Seo, J. Cheon, Acc. Chem. Res. 41, 179–189 (2008)

    Article  CAS  Google Scholar 

  10. I. Washio, Y. Xioung, Y. Yin, Y. Xia, Adv. Mater. 18, 1745–1749 (2006)

    Article  CAS  Google Scholar 

  11. S. Shylesh, V. Schünemann, W.R. Thiel, Angew Chem. Int. Ed. 49, 3428–3459 (2010)

    Article  CAS  Google Scholar 

  12. R.J. White, R. Luque, V.L. Budarin, J.H. Clark, D.J. Macquarrie, Chem. Soc. Rev. 38, 481–494 (2009)

    Article  CAS  Google Scholar 

  13. S. Shylesh, P. Prinson, P. Samuel, S. Sisodia, A.D. Singh, Catal. Surv. Asia 12, 266–282 (2008)

    Article  CAS  Google Scholar 

  14. U. Jeong, X. Teng, Y. Wang, Y. Xia, Adv. Mater. 19, 33–60 (2007)

    Article  CAS  Google Scholar 

  15. G.A. Mansoori, T. Rohani, A. Ahmadpour, Z. Eshghi, Annu. Rev. Nano Res. 2, 48–50 (2008)

    Google Scholar 

  16. G. Budroni, A. Corma, Angew. Chem. Int. Ed. Engl. 45, 3328–3331 (2006)

    Article  CAS  Google Scholar 

  17. A. Hu, G.T. Yee, W. Lin, J. Am. Chem. Soc. 127, 12486–12487 (2005)

    Article  CAS  Google Scholar 

  18. N.A. Frey, S. Peng, K. Cheng, S. Sun, Chem. Soc. Rev. 38, 2532–2542 (2009)

    Article  CAS  Google Scholar 

  19. R.B. Nasir Baig, R.S. Varma, Chem. Commun. 49, 752–770 (2013)

    Article  Google Scholar 

  20. M. Mokhtary, M. Torabi, J. Saudi Chem. Soc. (2014). doi:10.1016/j.jscs.2014.03.009

    Google Scholar 

  21. M. Nikpassand, L. Zare, T. Shafaati, S. Shariati, Chin. J. Chem. 30, 604–608 (2012)

    Article  CAS  Google Scholar 

  22. B. Karimi, S. Nikoseresht, S. Khodabakhshi, Chin. J. Catal. 33, 298–301 (2012)

    Article  Google Scholar 

  23. L.M. Liz-Marzán, M. Giersig, P. Mulvaney, Chem. Commun., 731–732 (1996)

  24. W. Stöber, A. Fink, E.J. Bohn, J. Colloid Interface Sci. 26, 62–69 (1968)

    Article  Google Scholar 

  25. P. Tartaj, C.J. Serna, J. Am. Chem. Soc. 125, 15754–15755 (2003)

    Article  CAS  Google Scholar 

  26. A.P. Philipse, M.P.B. van Bruggen, C. Pathmamanoharan, Langmuir 10, 92–99 (1994)

    Article  CAS  Google Scholar 

  27. Y.H. Deng, C.C. Wang, J.H. Hu, W.L. Yang, S.K. Fu, Colloid Surface A 262, 87–92 (2005)

    Article  CAS  Google Scholar 

  28. L.M. Liz-Marzán, M. Giersig, P. Mulvaney, Langmuir 12, 4329–4335 (1996)

    Article  Google Scholar 

  29. M. Giersig, M. Hilgendorff, Eur. J. Inorg. Chem., 3571–3583 (2005)

  30. R.P. Hodgkins, A. Ahniyaz, K. Parekh, L.M. Belova, L. Bergström, Langmuir 23, 8838–8844 (2007)

    Article  CAS  Google Scholar 

  31. N.C. King, R.A. Blackley, M.L. Wears, D.M. Newman, W.Zhou, D.W. Bruce, Chem. Commun., 3414–3416 (2006)

  32. Y. Li, T. Kaneko, T. Ogawa, M. Takahashi, R. Hatakeyama, Chem. Commun., 254–256 (2007)

  33. J. Lee, J. Kim, T. Hyeon, Adv. Mater. 18, 2073–2094 (2006)

    Article  CAS  Google Scholar 

  34. J. Grunes, J. Zhu, G.A. Somorjai, Chem. Commun., 2257–2260 (2003)

  35. M. Mokhtary, A. Mossafaii Rad, Int. Nano Lett. 5, 109–123 (2015)

    Article  Google Scholar 

  36. M. Mokhtary, N. Shahrivar Fallah, J. Taibah Univ. Sci. 9, 531–537 (2015)

    Article  Google Scholar 

  37. J.M. Thomas, W.J. Thomas, Principles and Practice of Heterogeneous Catalysis (VCH, Weinheim, 1997)

    Google Scholar 

  38. J. Fan, Y. Gao, J. Exp. Nanosci. 1, 457–475 (2006)

    Article  CAS  Google Scholar 

  39. A. Schätz, Dissertation, Universität Regensburg (2009)

  40. D. Enders, O. Niemeier, A. Henseler, Chem. Rev. 107, 5606–5655 (2007)

    Article  CAS  Google Scholar 

  41. M. Gruttadauria, F. Giacalone, R. Noto, Chem. Soc. Rev. 37, 1666–1688 (2008)

    Article  CAS  Google Scholar 

  42. A. Bruckmann, A. Krebs, C. Bolm, Green Chem. 10, 1131–1141 (2008)

    Article  CAS  Google Scholar 

  43. Y. Zheng, C. Duanmu, Y. Gao, Org. Lett. 8, 3215–3217 (2006)

    Article  CAS  Google Scholar 

  44. V. Polshettiwar, R.S. Varma, Tetrahedron 66, 1091–1097 (2010)

    Article  CAS  Google Scholar 

  45. R. Luque, B. Baruwati, R.S. Varma, Green Chem. 12, 1540–1543 (2010)

    Article  CAS  Google Scholar 

  46. F. Nemati, R. Saeedirad, Chin. Chem. Lett. 24, 370–372 (2013)

    Article  CAS  Google Scholar 

  47. H. Kefayati, M. Golshekan, S. Shariati, M. Bagheri, Chin. J. Catal. 36, 572–576 (2015)

    Article  CAS  Google Scholar 

  48. H. Mahmoudi, A.A. Jafari, S. Saeedi, H. Firouzabadi, RSC Adv. 5, 3023–3030 (2015)

    Article  CAS  Google Scholar 

  49. A. Alizadeh, M.M. Khodaei, M. Beygzadeh, D. Kordestani, M. Feyzi, Bull. Korean Chem. Soc. 33, 2546–2552 (2012)

    Article  CAS  Google Scholar 

  50. S.M. Sadeghzadeh, Chem. Plus. Chem. 79, 278–283 (2014)

    CAS  Google Scholar 

  51. B. Karimi, E. Farhangi, Chem. Eur. J. 17, 6056–6060 (2011)

    Article  CAS  Google Scholar 

  52. Y. Kong, L. Zhao, D. Yin, Green Chem. 15, 2422–2433 (2013)

    Article  CAS  Google Scholar 

  53. J. Safari, S. Gandomi-Ravandi, RSC Adv. 4, 11486–11492 (2014)

    Article  CAS  Google Scholar 

  54. V.I. Parvulescu, C. Hardacre, Chem. Rev. 107, 2615–2665 (2007)

    Article  CAS  Google Scholar 

  55. S. Sahoo, P. Coumar, F. Lefebvre, S.B. Halligudi, Appl. Catal. A. Gen. 354, 17–25 (2009)

    Article  CAS  Google Scholar 

  56. J. Miao, H. Wan, G. Guan, Catal. Commun. 12, 353–356 (2011)

    Article  CAS  Google Scholar 

  57. A. Zarrouk, M. Messali, H. Zarrok, R. Salghi, A.A. Ali, B. Hammouti, S.S. Al-Deyab, F. Bentiss, Int. J. Electrochem. Sci. 7, 6998–7015 (2012)

    CAS  Google Scholar 

  58. J. Safari, Z. Zarnegar, C. R. Chim. 16, 920–928 (2013)

    Article  CAS  Google Scholar 

  59. N. Azgomi, M. Mokhtary, J. Mol. Catal. A: Chem. 398, 58–64 (2015)

    Article  CAS  Google Scholar 

  60. M. Shafiee, A.R. Khosropour, I. Mohammadpoor-Baltork, M. Moghadam, S. Tangestaninejad, V. Mirkhani, Catal. Sci. Technol. 2, 2440–2444 (2012)

    Article  CAS  Google Scholar 

  61. H. Hamadi, N. Adibpour, J. Mol. Catal. A: Chem. 373, 25–29 (2013)

    Article  CAS  Google Scholar 

  62. A. Khalafi-Nezhad, S. Mohammadi, ACS Comb. Sci. 15, 512–518 (2013)

    Article  CAS  Google Scholar 

  63. P.H. Li, B.L. Li, H.C. Hu, Z.H. Zhang, Catal. Commun. 46, 118–122 (2014)

    Article  CAS  Google Scholar 

  64. S. Sobhani, Z. Pakdin-Parizi, Appl. Catal. A: Gen. 479, 112–120 (2014)

    Article  CAS  Google Scholar 

  65. L. Wang, J. Luo, M.M. Maye, Q. Fan, Q. Rendeng, M.H. Engelhard, C. Wang, Y. Lin, C.J. Zhong, J. Mater. Chem. 15, 1821–1832 (2005)

    Article  CAS  Google Scholar 

  66. C.-H. Jun, Y.J. Park, Y.R. Yeon, J.-R. Choi, W.-R. Lee, S.-J. Ko, J. Cheon, Chem. Commun., 1619–1621 (2006)

  67. C. Xu, J. Xie, D. Ho, C. Wang, N. Kohler, E.G. Walsh, J.R. Morgan, Y.E. Chin, S. Sun, Angew. Chem. Int. Ed. 47, 173–176 (2008)

    Article  CAS  Google Scholar 

  68. M. Esmaeilpour, A.R. Sardarian, J. Javidi, Appl. Catal. A: Gen. 445–446, 359–367 (2012)

    Article  Google Scholar 

  69. M. Esmaeilpour, A.R. Sardarian, J. Javidi, J. Organomet. Chem. 749, 233–240 (2014)

    Article  CAS  Google Scholar 

  70. R.K. Sharma, Y. Monga, Appl. Catal. A: Gen. 454, 1–10 (2013)

    Article  CAS  Google Scholar 

  71. M.S. Saeedi, S. Tangestaninejad, M. Moghadam, V. Mirkhani, I. Mohammadpoor-Baltork, A.R. Khosropour, Polyhedron 49, 158–166 (2013)

    Article  CAS  Google Scholar 

  72. L. Wang, M. Wang, P. Li, L. Wang, Appl. Organomet. Chem. 26, 576–582 (2012)

    Article  CAS  Google Scholar 

  73. M. Tajbakhsh, M. Farhang, S.M. Baghbanian, R. Hosseinzadeh, M. Tajbakhsh, New J. Chem. 39, 1827–1839 (2015)

    Article  CAS  Google Scholar 

  74. R. Abu-Reziq, D. Wang, M. Post, H. Alper, Adv. Synth. Catal. 349, 2145–2150 (2007)

    Article  CAS  Google Scholar 

  75. S. Lijuan, H. Jin, S. An, D. Ren, Chin. J. Catal. 34, 1378–1385 (2013)

    Article  Google Scholar 

  76. V. Khakyzdeh, R. Luque, M.A. Zolfigol, H.R. Vahidian, H. Salehzadeh, V. Moradi, A.R. Soleymani, A.R. Moosavi-Zare, K. Xu, RSC Adv. 5, 3917–3921 (2015)

    Article  Google Scholar 

  77. D.A. Tomalia, H. Baker, J. Dewald, M. Hall, G. Kallos, S. Martin, J. Roeck, J. Ryder, P. Smith, Poly. J. 17, 117–132 (1985)

    Article  CAS  Google Scholar 

  78. G.R. Newkome, Z. Yao, G.R. Baker, V.K. Gupta, J. Org. Chem. 50, 2003–2004 (1985)

    Article  CAS  Google Scholar 

  79. D. Astruc, E. Boisselier, C. Ornelas, Chem. Rev. 110, 1857–1959 (2010)

    Article  CAS  Google Scholar 

  80. Q.M. Kainz, O. Reiser, Acc. Chem. Res. 47, 667–677 (2014)

    Article  CAS  Google Scholar 

  81. R. Abu-Reziq, H. Alper, D. Wang, M.L. Post, J. Am. Chem. Soc. 128, 5279–5282 (2006)

    Article  CAS  Google Scholar 

  82. N. Pothayee, S. Balasubramaniam, R.M. Davis, J.S. Riffle, M.R.J. Carroll, R. Woodward, T. St Pierre, Polymer 52, 1356–1366 (2011)

    Article  CAS  Google Scholar 

  83. F. Hu, K.G. Neoh, L. Cen, E.T. Kang, Biomacromolecules 7, 809–816 (2006)

    Article  CAS  Google Scholar 

  84. I. Nakatani, M. Hijikata, K. Ozawa, J. Magn. Magn. Mater. 122, 10–14 (1993)

    Article  CAS  Google Scholar 

  85. N.A.D. Burke, H.D.H. Stöver, F.P. Dawson, Chem. Mater. 14, 4752–4761 (2002)

    Article  CAS  Google Scholar 

  86. P.D. Stevens, J. Fan, H.M.R. Gardimalla, M. Yen, Y. Gao, Org. Lett. 7, 2085–2088 (2005)

    Article  CAS  Google Scholar 

  87. M.M. Lakouraj, F. Hasanzadeh, E.N. Zare, Iran. Polym. J. 23, 933–945 (2014)

    Article  CAS  Google Scholar 

  88. J. Govan, Y.K. Gun’ko, Nanomaterials 4, 222–241 (2014)

    Article  CAS  Google Scholar 

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Acknowledgments

Financial support by Rasht Branch, Islamic Azad University, Grant No. 4.5830 is gratefully acknowledged.

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  1. Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, Iran

    Masoud Mokhtary

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Mokhtary, M. Recent advances in catalysts immobilized on magnetic nanoparticles. J IRAN CHEM SOC 13, 1827–1845 (2016). https://doi.org/10.1007/s13738-016-0900-4

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