Skip to main content
SpringerLink
Log in

Two new palladium and platinum complexes with a bidentate pyrazole-based ligand: crystal structure, fluorescence and Hirshfeld surface analysis

  • Original Paper
  • Published:
Journal of the Iranian Chemical Society Aims and scope Submit manuscript

Abstract

Two new precious metal coordination complexes [Pd(HL)2] (1) and [PtL2] (2) (where H2L is 1-(carboxymethyl)-1H-pyrazole-3-carboxylic acid) were synthesized by one-pot in situ hydrolysis. The complexes are assembled into a 3D structure by hydrogen bonding interactions and intermolecular contacts. The structures have been established by single-crystal X-ray diffraction, and characterized by FT-IR and liquid state fluorescent spectroscopy. Hirshfeld surface analysis reveals that the O···H contacts outnumber the other contacts in both structures (49.4 % of the total interactions for 1 and 41.6 % for 2).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Scheme 1
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. G. La Monica, G.A. Ardizzoia, Prog. Inorg. Chem. 46, 151 (1997)

    Article  Google Scholar 

  2. J. Pérez, L. Riera, Eur. J. Inorg. Chem. 33, 4913 (2009)

    Article  Google Scholar 

  3. M.A. Halcrow, Dalton Trans. 2059 (2009)

  4. J. Klingele, S. Dechert, F. Meyer, Coord. Chem. Rev. 253, 2698 (2009)

    Article  CAS  Google Scholar 

  5. R. Mukherjee, Coord. Chem. Rev. 203, 151 (2000)

    Article  CAS  Google Scholar 

  6. R.A. de Souza, A. Stevanato, O. Treu-Filho, A.V.G. Netto, A.E. Mauro, E.E. Castellano, I.Z. Carlos, F.R. Pavan, C.Q.F. Leite, Eur. J. Med. Chem. 45, 4863 (2010)

    Article  Google Scholar 

  7. R.Y. Mawo, D.M. Johnson, J.L. Wood, I.P. Smoliakova, J. Organomet. Chem. 693, 33 (2008)

    Article  CAS  Google Scholar 

  8. R.W.Y. Sun, D.L. Ma, E.L.M. Wong, C.M. Che, Dalton Trans. 4883 (2007)

  9. J.M. Lehn, Science 260, 1762 (1993)

    Article  CAS  Google Scholar 

  10. M. Guerrero, J. Pons, J. Ros, J. Organomet. Chem. 695, 1957 (2010)

    Article  CAS  Google Scholar 

  11. H. Zhao, Z.J. Chu, G.Y. Gao, H.H. Huang, Z.R. Qu, Polyhedron 83, 143 (2014)

    Article  CAS  Google Scholar 

  12. G.M. Sheldrick, Acta Cryst. C71, 3–8 (2015)

    Google Scholar 

  13. J. Pons, G. Aragay, J. Garcí-Antón, T. Calvet, M. Font-Bardia, J. Ros, Inorg. Chim. Acta 363, 911 (2010)

    Article  CAS  Google Scholar 

  14. J. Pons, A. Chadghan, J. Casabó, A. Alvarez-Larena, J.F. Piniella, J. Ros, Inorg. Chem. Commun. 3, 296 (2000)

    Article  CAS  Google Scholar 

  15. M.D. Ward, J.S. Fleming, E. Psillakis, J.C. Jeffery, J.A. McCleverty, Acta Cryst. C54, 609 (1998)

    CAS  Google Scholar 

  16. N.T.S. Phan, D.H. Brown, H. Adams, S.E. Spey, P. Styring, Dalton Trans. 1348 (2004)

  17. A.J. Canty, N.J. Minchin, J.M. Patrick, A.H. White, J. Chem. Soc., Dalton Trans. 1253 (1983)

  18. A.J. Canty, T. Honeyman, B.W. Skelton, A.H. White, J. Organomet. Chem. 430, 245 (1992)

    Article  CAS  Google Scholar 

  19. F.A. Allen, O. Kennard, Chem. Des. Autom. News 8, 31 (1993)

    Google Scholar 

  20. C. Tessier, F.D. Rochon, Inorg. Chim. Acta 373, 22 (2001)

    Google Scholar 

  21. M. Munakata, L.P. Wu, M. Yamamoto, T. Kurodasowa, M. Maekawa, S. Kawata, S. Kitagawa, J. Chem. Soc., Dalton Trans. 4099 (1995)

  22. S.K. Wolff, D.J. Grimwood, J.J. McKinnon, M.J. Turner, D. Jayatilaka, M.A. Spackman, Crystal Explorer version 3.1, 2013 (University of Western Australia: Perth)

  23. J.J. McKinnon, M.A. Spackman, A.S. Mitchell, Acta Cryst. Sect. B60, 627 (2004)

    Article  CAS  Google Scholar 

  24. D. Spackman, Jayatilaka. Cryst. Eng. Comm. 11, 19 (2009)

    Article  CAS  Google Scholar 

  25. J.J. McKinnon, D. Jayatilaka, M.A. Spackman, Chem. Commun. 3814 (2007)

  26. M. Pourayoubi, S. Shoghpour Bayraq, A. Tarahhomi, M. Nečas, K. Fejfarova, M. Dušek, J. Organomet. Chem. 751, 508 (2014)

    Article  CAS  Google Scholar 

  27. A. Tarahhomi, M. Pourayoubi, J.A. Golen, P. Zargaran, B. Elahi, A.L. Rheingold, M.A. Leyva Ramírez, T. Mancilla Percino, Acta Cryst. B69, 260 (2013)

Download references

Acknowledgments

We gratefully acknowledge the financial support of the National Natural Science Foundation of China (20801012) and the financial support from Jiangsu Ainaji Neoenergy Science and Technology Co., Ltd (8507040091).

Author information

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing, 211189, People’s Republic of China

    Chao Feng, Xue-Jing Li, Duo Zhang & Hong Zhao

  2. Key Laboratory of Organosilicon Chemistry and Material Technology of the Ministry of Education, Hangzhou Normal University, Hangzhou, 311121, People’s Republic of China

    Zhi-Rong Qu

Authors
  1. Chao Feng
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xue-Jing Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Duo Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhi-Rong Qu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Hong Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Zhi-Rong Qu or Hong Zhao.

Electronic supplementary material

Below is the link to the electronic supplementary material.

13738_2015_797_MOESM1_ESM.doc

CCDC 1061337 and 1061338 contain the supplementary crystallographic data for complexes 1 and 2. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via http://www.ccdc.cam.ac.uk/data_request/cif. (DOC 206 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Feng, C., Li, XJ., Zhang, D. et al. Two new palladium and platinum complexes with a bidentate pyrazole-based ligand: crystal structure, fluorescence and Hirshfeld surface analysis. J IRAN CHEM SOC 13, 823–830 (2016). https://doi.org/10.1007/s13738-015-0797-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s13738-015-0797-3

Keywords

Search

Navigation